Direct extraction of chitosan from snail shells by natural deep eutectic solvent

Q2 Chemistry Current Chemistry Letters Pub Date : 2023-01-01 DOI:10.5267/j.ccl.2023.1.001
Melody Kimi, Mohd Hazwan Hamdi
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引用次数: 1

Abstract

The processes involved to extract chitosan biopolymers from natural resources often employ hazardous chemicals and long processing time. This work provides a sustainable direct extraction method of chitosan from snail shells. Previous attempts using acetogenin in graviola extracts succeeded in the extraction of chitosan from marine shells. However, the slow reaction has prompted the addition of hydrogen bond acceptor solution into the graviola extract. Choline chloride is an excellent hydrogen bond acceptor mixed with acetogenin as hydrogen bond donor to form natural deep eutectic solvent (NADES) for the direct extraction of chitosan. Chitosan obtained from this method has a degree of deacetylation of 91% and a molecular weight of 481 kDa with fiber-like morphology. The direct extraction of chitosan from NADES consisting of choline chloride and acetogenin has proven to extract chitosan with comparable properties to commercial chitosan.
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天然深共晶溶剂直接提取蜗牛壳壳聚糖的研究
从自然资源中提取壳聚糖生物聚合物的过程通常使用有害化学物质,加工时间长。本研究为从蜗牛壳中提取壳聚糖提供了一种可持续的直接提取方法。在以前的尝试中,用醋酸原素在堇菜提取物中提取壳聚糖是成功的。然而,由于反应缓慢,使得在萃取物中加入了氢键受体溶液。氯化胆碱是一种很好的氢键受体,与乙酰胆碱混合为氢键给体,形成直接提取壳聚糖的天然深度共晶溶剂。该方法制备的壳聚糖脱乙酰度为91%,分子量为481 kDa,呈纤维状。从氯化胆碱和乙酰胆碱组成的NADES中直接提取壳聚糖,得到了与商品壳聚糖性能相当的壳聚糖。
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来源期刊
Current Chemistry Letters
Current Chemistry Letters Chemistry-Chemistry (all)
CiteScore
4.90
自引率
0.00%
发文量
27
审稿时长
20 weeks
期刊介绍: The "Current Chemistry Letters" is a peer-reviewed international journal which aims to publish all the current and outstanding research articles, reviews and letters in chemistry including analytical chemistry, green chemistry, inorganic chemistry, organic chemistry, physical chemistry, etc. This journal is dedicated to serve all academic and industrial researchers and scientists who are expert in all major advances in chemistry research. The journal aims to provide the most complete and reliable source of information on current developments in these fields. The emphasis will be on publishing quality articles rapidly and openly available to researchers worldwide. Please note readers are free to read, download, copy, distribute, print, search, or link to the full texts of articles published on this journal. Current Chemistry Letters is an open access journal, which provides instant access to the full text of research papers without any need for a subscription to the journal where the papers are published. Therefore, anyone has the opportunity to copy, use, redistribute, transmit/display the work publicly and to distribute derivative works, in any sort of digital form for any responsible purpose, subject to appropriate attribution of authorship. Authors who publish their articles may also maintain the copyright of their articles.
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