The properties of electrical conduction and photoconduction in polyphenylene sulfide by uniaxial elongation

U. Lee, T. Shin, Y.G. Park, K. Lim, S.H. Kang, B. Ryu
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Abstract

We have investigated how morphology and electrical properties in Polyphenylene sulfide (PPS) are changed by uniaxial elongation. XRD pattern shows that interplanar distance and crystallization are decreased by increasing elongation ratio. Electrical conduction mechanism of PPS is explained as Schottky emission from analysis of electrical current. The electrical current is decreased and the insulation resistivity is increased by increasing elongation ratio. The conductivity is changed remarkably above the glass transition temperature around 82/spl deg/C. The band gap of PPS is evaluated as 3.9 /spl sim/4 eV from the results of photoconductivity. Increasement of elongation ratio gives us some about deep trap formation from photocurrent.
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用单轴延伸法研究聚苯硫醚的电导和光导特性
我们研究了单轴延伸如何改变聚苯硫醚(PPS)的形态和电性能。XRD图谱表明,随着延伸率的增加,晶面间距和晶化程度减小。从电流分析出发,解释了PPS的导电机理为肖特基辐射。增大延伸率,减小电流,提高绝缘电阻率。在玻璃化转变温度82/spl℃以上,电导率发生显著变化。光电导率结果表明,PPS的带隙为3.9 /spl sim/4 eV。延长率的增加对光电流形成深阱有一定的启示。
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