Enhancing the Spectral Characteristics of Rhodamine 610 Laser Dye Doped with Chemically Prepared Gold Nanoparticles

Abu-Al-Hassan H. Ali, F. Mutlak
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Abstract

In this study, gold nanoparticle samples were prepared by the chemical reduction method (seed-growth) with 4 ratios (10, 12, 15 and 18) ml of seed, and the growth was stationary at 40 ml. The optical and structural properties of these samples were studied. The 18 ml seed sample showed the highest absorbance. The X- ray diffraction (XRD) patterns of these samples showed clear peaks at (38.25o, 44.5o, 64.4o, and 77.95o). The UV-visible showed that the absorbance of all the samples was in the same range as the standard AuNPs. The field emission-scanning electron microscope (FE-SEM) showed the shape of AuNPs as nanorods and the particle size between 30-50 nm. Rhodamine-610 (RhB) was prepared at 10-5 M concentration, the optical measurements were studied, AuNPs and RhB were mixed at ratios (1:1, 1:2, 1:3), and the fluorescence measurements were done. Full width at half maximum (FHWM) and the intensity of RhB after mixing were changed, and this result showed significant efficacy for many applications. The study shows that this mixing could be used after doping with polymer as a random gain medium or saturation absorber for pulse laser generation.
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化学制备金纳米粒子对罗丹明610激光染料光谱特性的增强
本研究采用化学还原法(种子生长法),以4种比例(10、12、15和18)ml的种子,在40 ml的稳定生长条件下制备了金纳米颗粒样品,并对样品的光学和结构性质进行了研究。18 ml的种子样品吸光度最高。样品的X射线衍射(XRD)谱图在(38.25,44.50,64.40,77.95)处有清晰的峰。紫外可见光谱显示,所有样品的吸光度与标准AuNPs在同一范围内。场发射扫描电镜(FE-SEM)显示AuNPs呈纳米棒状,粒径在30 ~ 50 nm之间。在10-5 M的浓度下制备罗丹明-610 (RhB),进行光学测量,将aunp和RhB按1:1、1:2、1:3的比例混合,并进行荧光测量。半最大全宽(FHWM)和混合后RhB的强度发生了变化,这一结果在许多应用中都显示出显著的效果。研究表明,聚合物掺杂后的混合物可作为脉冲激光产生的随机增益介质或饱和吸收剂。
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