Preliminary Characterization of Three Metallurgical Bauxite Residue Samples

P. Angelopoulos, Maria Georgiou, Paschalis Oustadakis, M. Taxiarchou, H. Karadağ, Y. Eker, G. Dobra, Alina Boiangiu, Gökhan Demir, S. Arslan, P. Davris, E. Balomenos
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引用次数: 2

Abstract

Bauxite Metallurgical Residue (BR) is a highly alkaline and very fine-grained by-product of the Bayer process for alumina production. Its huge global annual production has resulted in increasing accumulation of BR, causing deposition problems and serious environmental issues. RM contains oxides and salts of the main elements Fe, Al, Ca, Na, Si, Ti, and rare earths—REEs (Sc, Nd, Y, La, Ce, Ds)—many of which have been categorised by EU as critical metals (CMs). The valorisation of BR as a low-cost secondary raw material and metal resource could be a route for its reduction, introducing the waste into the economic cycle. REEScue constitutes a research project that aims to instigate the efficient exploitation of European bauxite residues, resulting from alumina production from Greece (MYTILINEOS SA), Turkey (ETI Aluminium), and Romania (ALUM SA), containing appreciable concentrations of scandium and REEs, through the development of a number of innovative extraction and separation technologies that can efficiently address the drawbacks of the existing solution. The consortium consists of three alumina producers from Greece (MYTILINEOS SA), Turkey (ETI Aluminium), and Romania (ALUM SA) and two academic partners from Greece (National Technical University of Athens) and Turkey (Necmettin Erbacan University). We present preliminary characterization results of three different BR samples that originate from the three aluminium industries, in respect of bulk chemical analysis (XRF, ICP), mineralogical investigation (XRD), and morphological observation through microscopy.
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三种冶金铝土矿渣样品的初步表征
铝土矿冶金渣(BR)是拜耳法生产氧化铝的高碱性和非常细粒度的副产品。其巨大的全球年产量导致BR的积累不断增加,造成沉积问题和严重的环境问题。RM含有主要元素Fe, Al, Ca, Na, Si, Ti的氧化物和盐,以及稀土- ree (Sc, Nd, Y, La, Ce, Ds) -其中许多已被欧盟归类为关键金属(CMs)。BR作为一种低成本的二次原料和金属资源的增值可能是减少BR的途径,将废物引入经济循环。rescue是一个研究项目,旨在通过开发一些创新的提取和分离技术,有效地解决现有解决方案的缺点,促进对欧洲铝土矿残留物的有效利用,这些铝土矿残留物来自希腊(MYTILINEOS SA)、土耳其(ETI aluminum)和罗马尼亚(ALUM SA)的氧化铝生产,其中含有可观浓度的钪和稀土。该财团由三家氧化铝生产商组成,分别来自希腊(MYTILINEOS SA)、土耳其(ETI aluminum)和罗马尼亚(ALUM SA),以及来自希腊(雅典国立技术大学)和土耳其(Necmettin Erbacan大学)的两家学术合作伙伴。我们提出了来自三个铝工业的三种不同BR样品的初步表征结果,包括大量化学分析(XRF, ICP),矿物学研究(XRD)和显微镜形态观察。
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