Hydrothermal Synthesis, Crystal Structure, and Luminescent Property of a New Cd(II) Coordination Polymer With Three-Fold Interpenetrated pcu Topology

Xiuling Feng, Wanping Chen, B. Xiang
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引用次数: 0

Abstract

A new three-dimensional (3D) coordination polymer, [Cd(pda)(bib)0.5] n(1), [H2pda=1,4-phenylenediacetic acid and bib=1,4-bis(2-methyl-imidazol-1-yl) butane] was prepared by hydrothermal syntheses and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, and elemental analysis. Crystal structure determination revealed that complex 1 features a threefold interpenetrated pcu framework. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.
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一种具有三层互穿pcu拓扑结构的新型Cd(II)配位聚合物的水热合成、晶体结构和发光性能
采用水热合成方法制备了一种新的三维配位聚合物[Cd(pda)(bib)0.5] n(1), [H2pda=1,4-苯二乙酸,bib=1,4-双(2-甲基咪唑-1-基)丁烷],并用单晶x射线衍射、FT-IR光谱和元素分析对其进行了表征。晶体结构测定表明,配合物1具有三层互穿pcu框架。此外,还研究了配合物1在室温下的固态发光特性。
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