Suvidha Sehrawat, Alish Mahajan, N. Sandhu, V. Anand, V. S. Rana, A. P. Singh, R. Yadav, Ashutosh Kumar Singh
{"title":"Novel schiff base as Fe3+ sensor as well as an antioxidant and its theoretical studies","authors":"Suvidha Sehrawat, Alish Mahajan, N. Sandhu, V. Anand, V. S. Rana, A. P. Singh, R. Yadav, Ashutosh Kumar Singh","doi":"10.3233/mgc-220076","DOIUrl":null,"url":null,"abstract":"A novel Schiff base derivative L (N1-(thiophene-2-ylmethylene)benzene-1,2-diamine) was synthesized via condensation reaction of 3-thiophene carboxaldehyde and 1,2-diamino benzene. The synthesized compound was authenticated using 1 H NMR, 13 C NMR, HRMS, and IR spectroscopy. The compound L was found to be a Fe3+ sensor with the complexation ratio of 1 : 3 as revealed by Job’s plot with maximum absorption at 318 nm. The photophysical properties were studied using absorption and emission spectra. DFT and TD-DFT studies were carried out in order to support the photophysical outcomes of compound L. An antioxidant behaviour of compound L was studied using TAC, FRAP, and DPPH assays and it was found to be showing better TAC activity than the used standard i.e. gallic acid.","PeriodicalId":18027,"journal":{"name":"Main Group Chemistry","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Main Group Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3233/mgc-220076","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A novel Schiff base derivative L (N1-(thiophene-2-ylmethylene)benzene-1,2-diamine) was synthesized via condensation reaction of 3-thiophene carboxaldehyde and 1,2-diamino benzene. The synthesized compound was authenticated using 1 H NMR, 13 C NMR, HRMS, and IR spectroscopy. The compound L was found to be a Fe3+ sensor with the complexation ratio of 1 : 3 as revealed by Job’s plot with maximum absorption at 318 nm. The photophysical properties were studied using absorption and emission spectra. DFT and TD-DFT studies were carried out in order to support the photophysical outcomes of compound L. An antioxidant behaviour of compound L was studied using TAC, FRAP, and DPPH assays and it was found to be showing better TAC activity than the used standard i.e. gallic acid.
期刊介绍：
Main Group Chemistry is intended to be a primary resource for all chemistry, engineering, biological, and materials researchers in both academia and in industry with an interest in the elements from the groups 1, 2, 12–18, lanthanides and actinides. The journal is committed to maintaining a high standard for its publications. This will be ensured by a rigorous peer-review process with most articles being reviewed by at least one editorial board member. Additionally, all manuscripts will be proofread and corrected by a dedicated copy editor located at the University of Kentucky.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
