Optimum Radius Size between Cylindrical Ion Trap and Quadrupole Ion Trap

IF 0.4 Q4 SPECTROSCOPY Mass Spectrometry Letters Pub Date : 2015-09-30 DOI:10.5478/MSL.2015.6.3.59
S. S. Chaharborj, S. Kiai, N. Arifin, Y. Gheisari
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引用次数: 3

Abstract

Quadrupole ion trap mass analyzer with a simplified geometry, namely, the cylindrical ion trap (CIT), has been shown to be well-suited using in miniature mass spectrometry and even in mass spectrometer arrays. Computation of stability regions is of particular importance in designing and assembling an ion trap. However, solving CIT equations are rather more dif- ficult and complex than QIT equations, so, analytical and matrix methods have been widely used to calculate the stability regions. In this article we present the results of numerical simulations of the physical properties and the fractional mass resolu- tions of the confined ions in the first stability region was analyzed by the fifth order Runge-Kutta method (RKM5) at the optimum radius size for both ion traps. Because of similarity the both results, having determining the optimum radius, we can make much easier to design CIT. Also, the simulated results has been performed a high precision in the resolution of trapped ions at the optimum radius size.
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圆柱形离子阱和四极离子阱的最佳半径尺寸
四极离子阱质谱分析仪具有简化的几何形状,即圆柱形离子阱(CIT),已被证明非常适合用于微型质谱分析甚至质谱阵列。稳定区域的计算在离子阱的设计和组装中尤为重要。然而,求解CIT方程比求解QIT方程要困难和复杂得多,因此,分析和矩阵方法被广泛应用于稳定区域的计算。本文给出了两种离子阱在最佳半径尺寸下的物理性质的数值模拟结果,并用五阶龙格-库塔方法(RKM5)分析了第一稳定区内受限离子的分数质量分辨率。由于两种结果的相似性,确定了最佳半径,可以简化CIT的设计,并且模拟结果在最佳半径尺寸下对捕获离子的分辨率有较高的精度。
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来源期刊
CiteScore
0.90
自引率
20.00%
发文量
0
审稿时长
6 weeks
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