Solvent Extraction of Hydrochloric Acid Using Commercial Extractants and Synthesized Ionic Liquids

Hoa Nguyen Viet Nhan, Man-Seung Lee
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引用次数: 4

Abstract

The extraction and stripping of HCl from aqueous solutions by commercial extractants like LIX 63 and its mixture with TEHA/ Cyanex 923/ Aliquat 336 and ionic liquids like ALi-SCN, ALi-PC in kerosene was investigated. Among these extractants, ALi-PC showed the best extraction effectivity (above 80%), but it was difficult to strip HCl from the loaded phase. Although the extraction percentage of HCl by LIX 63 was not high, the stripping performance was above 81%. The addition of octanol to the organic phase led to negative effect on the extraction performance of HCl. The addition of C2H5OH into aqueous solutions significantly increased the extraction and stripping percentage of HCl by LIX 63, ALi-PC and ALi-SCN.
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用工业萃取剂和合成离子液体萃取盐酸
研究了商用萃取剂LIX 63及其与TEHA/ Cyanex 923/ Aliquat 336和离子液体ALi-SCN、ALi-PC对煤油水溶液中HCl的萃取和剥离。在这些萃取剂中,ALi-PC萃取效率最高(80%以上),但很难从负载相中剥离HCl。虽然lix63对HCl的萃取率不高,但溶出率均在81%以上。在有机相中加入辛醇对HCl的萃取性能有不利影响。水溶液中加入C2H5OH可显著提高LIX 63、ALi-PC和ALi-SCN对HCl的萃取和提提率。
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