Numerical Simulation of Thermal Performance for the Reaction Tubes in a Miniaturized Methanol Synthesis Reactor

K. Xiong, Yongli Yin, Yong Cao, Xiaotian Liu
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Abstract

The reaction of methanol synthesis via hydrogen and carbon dioxide which has a broad application prospect in the energy field should be carried out in a reasonable temperature range. Thus, a comprehensive thermal analysis under different work conditions for the reaction tube which is the really reaction place in the miniaturized methanol synthesis reactor is of great significance to its temperature control and thermal design. In this paper, the thermal analysis models of reaction tube in methanol synthesis reactor via hydrogen and carbon dioxide are established, through numerical simulation, the thermal performance results which include the molar ratio of methanol synthesis and temperature distribution inside reaction tubes changing with the reaction tube diameter, inlet gas temperature, and space velocity are obtained. Based on the results, the change laws of the methanol synthesis molar ratio and temperature distribution change with the three parameters are summed, which provide a reference to the thermal design and working conditions setting for the miniaturized methanol synthesis reactor of hydrogen and carbon dioxide.
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小型甲醇合成反应器反应管热性能的数值模拟
氢气与二氧化碳合成甲醇的反应在能源领域具有广阔的应用前景,应在合理的温度范围内进行。因此,对小型甲醇合成反应器中真正的反应场所——反应管进行不同工况下的综合热分析,对其温度控制和热设计具有重要意义。本文建立了氢气和二氧化碳作用下甲醇合成反应器反应管的热分析模型,通过数值模拟得到了甲醇合成摩尔比和反应管内温度分布随反应管直径、入口气体温度和空速变化的热性能结果。在此基础上,总结了甲醇合成摩尔比和温度分布随这三个参数的变化规律,为氢-二氧化碳微型甲醇合成反应器的热设计和工况设置提供参考。
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