Effect of shell thickness on heterostructure of CdSe/CdS core/shell nanocrystals

A. Le, Minh Tan Man, M. H. Nguyen
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Abstract

Core/shell hetero-nanostructures are promising materials for fabricating optoelectronic devices, photodetectors, bioimaging, and biosensing. The CdSe/CdS core/shell nanocrystals (NCs) were synthesized in a wet chemical reaction. The shell thickness was modified by varying reaction times. The structure and optical properties as a function of the CdS shell thickness were investigated. A systematic redshift of the first exciton absorption peaks and photoluminescent (PL) spectra occurred after coating with CdS confirmed the shell growth over the CdSe core. The PL's intensity increased compared with that of bare NCs. The formation of high-quality NCs with uniform size distribution was shown in the transmission electron microscopy (TEM) image and confirmed by the narrow PL band and small FWHM.
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壳层厚度对CdSe/CdS核壳纳米晶异质结构的影响
核壳异质纳米结构在光电器件、光电探测器、生物成像和生物传感等领域具有广阔的应用前景。采用湿法合成了CdSe/CdS核壳纳米晶体。壳层厚度随反应时间的变化而变化。研究了CdS的结构和光学性质随壳层厚度的变化规律。涂覆CdS后,第一激子吸收峰和光致发光(PL)光谱发生了系统的红移,证实了CdSe核心上的壳生长。与裸nc相比,PL的强度有所增加。透射电镜(TEM)图像显示形成了尺寸分布均匀的高质量nc,并通过较窄的PL波段和较小的FWHM证实了这一点。
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