Radioluminescence of methylcyclohexane in the glassy state

J. Kroh, R. Leszczyński, J. Mayer
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引用次数: 3

Abstract

The radioluminescence of pure, frozen methylcyclohexane (MCH) has been investigated. λ-Irradiation of MCH at 77 K produces at least three negative species—trapped electrons, e-t, and two types of anions, which are formed in the reactions of electrons with radicals, R-, and with stable radiolysis products, P-. It is shown that the radiothermoluminescence (RTL) emission is due to the recombination of et-(RTL peak at 90 K) and R-, P- (RTL peak at 95 K) with cations. The intensity-dose dependence of the RTL peaks has been interpreted using a simple kinetic model.

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甲基环己烷在玻璃态的放射发光
研究了冷冻纯甲基环己烷(MCH)的放射发光特性。在77 K下辐照MCH会产生至少3种负电荷——捕获电子e-t和两种阴离子,它们是由电子与自由基R-和稳定的辐射分解产物P-反应形成的。结果表明,辐射热释光(RTL)发射是由et-(RTL峰在90k)和R-、P- (RTL峰在95k)与阳离子复合引起的。用一个简单的动力学模型解释了RTL峰的强度剂量依赖性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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