Rare-Earth-Iron-Boron permanent magnets by rapid solidification processing

J.J. Croat
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Abstract

The development of a light-rare-earth-iron-based permanent magnet has been a long standing goal of the permanent magnet industry. The first successful attempts at magnetically hardening these materials employed rapid solidification techniques. This work culminated in the discovery of the NdFeB-based permanent magnet materials, the properties of which have been shown to derive from the Nd2Fe14B intermetallic phase. This class of magnets has received considerable scientific and commercial interest stemming from the fact that energy products already significantly exceed those of the SmCo-based materials. Moreover, owing to the relative abundance of neodymium, the cost of these materials is potentially much lower.

Processing these magnets is carried out by two distinctly different techniques. These include the conventional powder metal-sinter process and consolidation of rapidly solidified materials. This paper discusses the preparation of these materials by the latter method. Included are the properties of the rapidly solidified ribbons themselves, methods for consolidating these materials into monolithic magnet shapes, microstructural data, and long-term thermal aging characteristics.

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稀土-铁-硼永磁体的快速凝固加工
研制轻稀土铁基永磁体一直是永磁工业长期追求的目标。对这些材料进行磁硬化的第一次成功尝试采用了快速凝固技术。这项工作最终发现了NdFeb基永磁材料,其性能已被证明源自Nd2Fe14B金属间相。这类磁铁已经获得了相当大的科学和商业兴趣,因为能源产品已经大大超过了Smco基材料。此外,由于钕的相对丰富,这些材料的成本可能要低得多。加工这些磁铁采用两种截然不同的技术。这包括传统的粉末金属烧结工艺和快速凝固材料的固结。本文讨论了后一种方法制备这些材料。包括快速固化带本身的特性,将这些材料固化成单片磁铁形状的方法,微观结构数据和长期热老化特性。
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