A. Maltha, S.C. van Wermeskerken, B. Brunet, V. Ponec
{"title":"Transition metal oxides as catalysts for the selective reduction of nitrobenzene","authors":"A. Maltha, S.C. van Wermeskerken, B. Brunet, V. Ponec","doi":"10.1016/0304-5102(94)00121-9","DOIUrl":null,"url":null,"abstract":"<div><p>The activity of various 3d, 4d and 5d transition metal oxides in the selective reduction of nitrobenzene to nitrosobenzene has been investigated. An attempt has been made to find a correlation between these activities and several properties of the oxides investigated, such as their place in the Periodic Table, structure, reducibility, heat of formation and surface metal—oxygen bond strength. A weak volcano-shape correlation can be seen with the heat of formation and the surface metal—oxygen bond strength.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"93 3","pages":"Pages 305-316"},"PeriodicalIF":0.0000,"publicationDate":"1994-10-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)00121-9","citationCount":"11","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294001219","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
引用次数: 11
Abstract
The activity of various 3d, 4d and 5d transition metal oxides in the selective reduction of nitrobenzene to nitrosobenzene has been investigated. An attempt has been made to find a correlation between these activities and several properties of the oxides investigated, such as their place in the Periodic Table, structure, reducibility, heat of formation and surface metal—oxygen bond strength. A weak volcano-shape correlation can be seen with the heat of formation and the surface metal—oxygen bond strength.
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