Factors controlling the reactivity of the silica surface in methane partial oxidation

A. Parmaliana *, F. Frusteri, D. Miceli, A. Mezzapica, M.S. Scurrell, N. Giordano
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引用次数: 29

Abstract

Catalytic partial oxidation of methane with oxygen on several oxide supports has been studied by using a batch reactor. The reactivity of various commercial SiO2 samples at 520°C (“precipitated”, “extruded”, “gel” and “fumed”), expressed in terms of space time yield to HCHO, has been particularly ascertained with reference to their preparation method and sodium content. The “highest” activity of the “precipitated” SiO2 sample is further enhanced by heat-treatment at 1000°C.

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甲烷部分氧化过程中二氧化硅表面反应性的控制因素
采用间歇式反应器研究了几种氧化载体上的甲烷部分氧化反应。各种商业SiO2样品在520°C(“沉淀”、“挤压”、“凝胶”和“气相”)下的反应性,以HCHO的时空产率表示,特别确定了它们的制备方法和钠含量。“沉淀”SiO2样品的“最高”活性在1000℃热处理后进一步增强。
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