Ion-molecule studies of energetic oxygen allotropes in flow tubes: O 2 ( v ) , O 2 ( a Δ g 1 ) , O 3 , and O ${{\rm{O}}}_{2}({\rm{v}}),{{\rm{O}}}_{2}({\rm{a}}{}^{1}{\rm{\Delta }}_{{\rm{g}}}),{{\rm{O}}}_{3},\mathrm{and}{\rm{O}}$.

IF 6.9 2区化学 Q1 SPECTROSCOPY Mass Spectrometry Reviews Pub Date : 2023-07-02 DOI:10.1002/mas.21846

Nicole Eyet, Shaun G Ard, Nicholas S Shuman, Albert A Viggiano

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Abstract

Starting in the 1960s, flow tube apparatuses have played a central role in the study of ion-molecule kinetics, allowing for immense chemical diversity of cationic, anionic, and neutral reactants. Here, we review studies of oxygen allotropes, excluding ground state O₂ ( $X^{3} \sum_{g}^{-}$ ), and focusing instead on reactions of cations, anions, and metal chemi-ionization reactions with ground state atomic oxygen (O ³ P), vibrationally excited molecular oxygen (O₂ (v)), electronically excited molecular oxygen (O₂ ( $a^{1} Δ_{g}$ )), and ozone (O₃ ). Historical outlines of work over several decades are given along with a focus on more recent work by our group at the Air Force Research Laboratory.

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流管离子分子的研究精力充沛的氧气的同素异形体:O 2 (v), O 2(Δg 1), O 3,和O $ {{\ rm {O}}} _ {2} ({\ rm {v}}), {{\ rm {O}}} _ {2} ({\ rm{一}}{}^ {1}{\ rm{\三角洲}}_ {{\ rm {g}}}), {{\ rm {O}}} _ {3}, \ mathrm{和}{\ rm {O}} $。

从20世纪60年代开始，流管装置在离子分子动力学研究中发挥了核心作用，允许阳离子，阴离子和中性反应物的巨大化学多样性。在这里，我们回顾了氧同素异体的研究，不包括基态O2 (X 3∑g - ${X}^{3}{\sum }_{g}^{-}$)，而是关注阳离子、阴离子和金属与基态原子氧(o3p)、振动激发分子氧(O2 (v))、电子激发分子氧(O2 (a 1 Δ g ${a}^{1}{{\rm{\Delta }}}_{g}$))和臭氧(O3)的化学电离反应。几十年来工作的历史概况以及我们在空军研究实验室的小组最近的工作重点。

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来源期刊

Mass Spectrometry Reviews 物理-光谱学

CiteScore

16.30

自引率

3.00%

发文量

期刊介绍： The aim of the journal Mass Spectrometry Reviews is to publish well-written reviews in selected topics in the various sub-fields of mass spectrometry as a means to summarize the research that has been performed in that area, to focus attention of other researchers, to critically review the published material, and to stimulate further research in that area. The scope of the published reviews include, but are not limited to topics, such as theoretical treatments, instrumental design, ionization methods, analyzers, detectors, application to the qualitative and quantitative analysis of various compounds or elements, basic ion chemistry and structure studies, ion energetic studies, and studies on biomolecules, polymers, etc.

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