{"title":"无过渡金属条件下苯乙烯与NH4SCN和水的多组分级联羟基磺化合成β-羟基硫化物。","authors":"Xian Liu, Liqiang Hao, Yangyang Wang, Yafei Ji","doi":"10.1002/asia.202300901","DOIUrl":null,"url":null,"abstract":"<p>Transition-mental-free multi-component hydroxysulfenylation of styrenes with NH<sub>4</sub>SCN and water to from <i>β</i>-hydroxysulfides is established. The reaction mechanism proceeded via a domino reaction after a radical addition to 2-phenylimidazo[1,2-<i>a</i>]pyridines. This approach features a wide substrate scope and functional group compatibility, providing 34 compounds in acceptable yields.</p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":"19 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of β-Hydroxysulfides via Multi-Component Cascade Hydroxysulfenylation of Styrenes with NH4SCN and Water under Transition-metal-free Conditions\",\"authors\":\"Xian Liu, Liqiang Hao, Yangyang Wang, Yafei Ji\",\"doi\":\"10.1002/asia.202300901\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Transition-mental-free multi-component hydroxysulfenylation of styrenes with NH<sub>4</sub>SCN and water to from <i>β</i>-hydroxysulfides is established. The reaction mechanism proceeded via a domino reaction after a radical addition to 2-phenylimidazo[1,2-<i>a</i>]pyridines. This approach features a wide substrate scope and functional group compatibility, providing 34 compounds in acceptable yields.</p>\",\"PeriodicalId\":145,\"journal\":{\"name\":\"Chemistry - An Asian Journal\",\"volume\":\"19 1\",\"pages\":\"\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2023-11-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - An Asian Journal\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/asia.202300901\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/asia.202300901","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of β-Hydroxysulfides via Multi-Component Cascade Hydroxysulfenylation of Styrenes with NH4SCN and Water under Transition-metal-free Conditions
Transition-mental-free multi-component hydroxysulfenylation of styrenes with NH4SCN and water to from β-hydroxysulfides is established. The reaction mechanism proceeded via a domino reaction after a radical addition to 2-phenylimidazo[1,2-a]pyridines. This approach features a wide substrate scope and functional group compatibility, providing 34 compounds in acceptable yields.
期刊介绍：
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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