{"title":"气体在恒压下发生爆炸反应","authors":"F.W. Stevens","doi":"10.1016/S1062-2888(65)80009-0","DOIUrl":null,"url":null,"abstract":"<div><p>The course of the gaseous explosive reaction at constant pressure is described and then followed experimentally by means of photographic time-volume records obtained by a simple device that is found to function as a transparent bomb of constant pressure. It is found that at constant pressure the uniform rate of propagation, <em>s</em>, of the zone of explosive reaction, when measured relative to the active gases, is proportional to the product of their concentrations (partial pressures): <span><span><span><math><mrow><mi>s</mi><mo>=</mo><msub><mi>k</mi><mn>1</mn></msub><msup><mrow><mo>[</mo><mi>A</mi><mo>]</mo></mrow><mrow><mi>n</mi><mn>1</mn></mrow></msup><msup><mrow><mo>[</mo><mo>B</mo><mo>]</mo></mrow><mrow><mi>n</mi><mn>2</mn></mrow></msup><msup><mrow><mo>[</mo><mi>C</mi><mo>]</mo></mrow><mrow><mi>n</mi><mn>3</mn></mrow></msup><mo>⋯</mo></mrow></math></span></span></span>.</p><p>In the light of this relationship studies have been made of the effect of inert gases and of composite fuels on the rate of the gaseous explosive transformation.</p></div>","PeriodicalId":101045,"journal":{"name":"Proceedings of the Symposium on Combustion","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1948-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1062-2888(65)80009-0","citationCount":"1","resultStr":"{\"title\":\"The gaseous explosive reaction at constant pressure\",\"authors\":\"F.W. Stevens\",\"doi\":\"10.1016/S1062-2888(65)80009-0\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The course of the gaseous explosive reaction at constant pressure is described and then followed experimentally by means of photographic time-volume records obtained by a simple device that is found to function as a transparent bomb of constant pressure. It is found that at constant pressure the uniform rate of propagation, <em>s</em>, of the zone of explosive reaction, when measured relative to the active gases, is proportional to the product of their concentrations (partial pressures): <span><span><span><math><mrow><mi>s</mi><mo>=</mo><msub><mi>k</mi><mn>1</mn></msub><msup><mrow><mo>[</mo><mi>A</mi><mo>]</mo></mrow><mrow><mi>n</mi><mn>1</mn></mrow></msup><msup><mrow><mo>[</mo><mo>B</mo><mo>]</mo></mrow><mrow><mi>n</mi><mn>2</mn></mrow></msup><msup><mrow><mo>[</mo><mi>C</mi><mo>]</mo></mrow><mrow><mi>n</mi><mn>3</mn></mrow></msup><mo>⋯</mo></mrow></math></span></span></span>.</p><p>In the light of this relationship studies have been made of the effect of inert gases and of composite fuels on the rate of the gaseous explosive transformation.</p></div>\",\"PeriodicalId\":101045,\"journal\":{\"name\":\"Proceedings of the Symposium on Combustion\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1948-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S1062-2888(65)80009-0\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Proceedings of the Symposium on Combustion\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1062288865800090\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the Symposium on Combustion","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1062288865800090","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The gaseous explosive reaction at constant pressure
The course of the gaseous explosive reaction at constant pressure is described and then followed experimentally by means of photographic time-volume records obtained by a simple device that is found to function as a transparent bomb of constant pressure. It is found that at constant pressure the uniform rate of propagation, s, of the zone of explosive reaction, when measured relative to the active gases, is proportional to the product of their concentrations (partial pressures): .
In the light of this relationship studies have been made of the effect of inert gases and of composite fuels on the rate of the gaseous explosive transformation.