{"title":"Fe3O4@[email protected]:一种磁性金属-有机骨架作为可回收催化剂用于硝基水化和还原异硫氰酸酯、异氰酸酯和异氰酸酯","authors":"Arash Ghorbani-Choghamarani*, Zahra Taherinia*","doi":"10.1021/acscombsci.0c00178","DOIUrl":null,"url":null,"abstract":"<p >A novel magnetic metal–organic framework (Fe<sub>3</sub>O<sub>4</sub>@[email?protected]) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and <i>isocyanides</i> with excellent activity and selectivity without any additional reducing agent.</p>","PeriodicalId":14,"journal":{"name":"ACS Combinatorial Science","volume":null,"pages":null},"PeriodicalIF":3.7840,"publicationDate":"2020-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1021/acscombsci.0c00178","citationCount":"10","resultStr":"{\"title\":\"Fe3O4@[email protected]: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides\",\"authors\":\"Arash Ghorbani-Choghamarani*, Zahra Taherinia*\",\"doi\":\"10.1021/acscombsci.0c00178\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A novel magnetic metal–organic framework (Fe<sub>3</sub>O<sub>4</sub>@[email?protected]) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and <i>isocyanides</i> with excellent activity and selectivity without any additional reducing agent.</p>\",\"PeriodicalId\":14,\"journal\":{\"name\":\"ACS Combinatorial Science\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7840,\"publicationDate\":\"2020-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1021/acscombsci.0c00178\",\"citationCount\":\"10\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Combinatorial Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acscombsci.0c00178\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"Chemistry\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Combinatorial Science","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acscombsci.0c00178","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Chemistry","Score":null,"Total":0}
Fe3O4@[email protected]: A Magnetic Metal–Organic Framework as a Recoverable Catalyst for the Hydration of Nitriles and Reduction of Isothiocyanates, Isocyanates, and Isocyanides
A novel magnetic metal–organic framework (Fe3O4@[email?protected]) has been prepared and characterized by spectroscopic, microscopic, and magnetic techniques. This magnetically separable catalyst exhibited high catalytic activity for nitrile hydration and the ability to reduce isothiocyanates, isocyanates, and isocyanides with excellent activity and selectivity without any additional reducing agent.
期刊介绍：
The Journal of Combinatorial Chemistry has been relaunched as ACS Combinatorial Science under the leadership of new Editor-in-Chief M.G. Finn of The Scripps Research Institute. The journal features an expanded scope and will build upon the legacy of the Journal of Combinatorial Chemistry, a highly cited leader in the field.
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