响应面法研究操作因素对塑料废弃物热解产生物油的影响

T. Ayodele, O. Durodola, A. Ogunjuyigbe, Josiah Lange Munda
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引用次数: 1

摘要

本文介绍了四种操作因素(塑料类型即原料、温度、升温速率和反应时间)对塑料废弃物热解生物油收率的影响。为了实现这一目标,我们从不同的文献中获取了27个不同类型塑料在不同热解操作条件下的不同热解实验,然后使用响应面法(RSM)建模。这是为了便于建立操作因素与塑料废弃物可能的生物油产率之间的回归关系,从而确定操作因素的影响。部分关键结果表明,基于RSM的回归模型可以有效地对4个操作因子进行建模和预测,其r平方值和调整后的r平方值分别为92.2%和83.2%。研究还表明,不同因素之间的相互作用会导致不同的生物油产量,因此需要确定影响因素之间的最佳相互作用,以获得最大的生物油产量。从结果可以看出,温度和塑料类型(原料)对生物油热解过程有很强的影响。过高或过低的温度以及用作原料的塑料类型都可能导致生物油产量的很大变化。反应时间的影响被认为是最小的,因为它几乎是恒定的所有调查场景。
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Effects of Operating Factors on the Bio-Oil Produced from Pyrolysis of Plastic Wastes using Response Surface Methodology
This paper presents the influence of four operating factors (plastic type i.e feedstock, temperature, heating rate and the reaction time) on the bio-oil yield obtainable from pyrolysis of plastics wastes. To achieve this, twenty-seven (27) different experiments conducted on the pyrolysis of various plastic types under different pyrolytic operating conditions were sourced from different literature and then modelled using response surface methodology (RSM). This is to facilitate the establishment of regression relationship between the operating factors and the probable bio-oil yield from plastic waste making it possible to determine the impact of the operating factors. Some of the key results show that the regression model derived from the RSM could effectively model and predict the bio oil yield using the four operating factors with the R–square and the adjusted R–square value of 92.2% and 83.2%, respectively. It is also revealed that the different interactions among the factors result into different bio-oil production, hence, the need for determining the best interaction among the influencing factors for maximum bio-oil production. It can be generally observed from the results that temperature and plastic type (feedstock) have very strong effect on pyrolysis process of bio-oil production. Too high or too low temperature as well as the type of plastic used as feedstock could cause a very high variation in the bio-oil yield. The effect of reaction time is seen to be minimal as it is nearly constant for all the investigated scenarios.
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