传统铸造和冷轧5754-Sc-Zr铝合金的机械、热学和电学特性

M. Vlach, V. Kodetová, H. Kudrnová, M. Leibner, M. Vlček, V. Šíma, I. Procházka, J. Málek, V. Očenášek
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摘要

研究了冷轧对Al-2.93wt.%Mg-0.34wt.%Mn-0.33wt.%Si-0.22wt.%Fe-0.19wt.%Cr-0.24wt.%Sc-0.06wt合金的力学、热学、电学性能和显微组织行为的影响。研究了%Zr。在从室温到540°C的温度范围内逐步等时退火和在200、450和550°C的等温退火期间对材料进行了研究。采用电阻法、电导率法、显微硬度法和差示扫描量热法研究了沉淀反应。硬化效应是由于Al3Sc和/或Al3(Sc,Zr)颗粒的额外析出而产生的。在~ 330℃以上,残余电阻率的显著变化可能是Mn (,Fe,Cr)颗粒析出所致。这种析出过程受冷轧的影响很大,但对硬度的影响可以忽略不计。测定了Al3Sc和/或Al3(Sc,Zr)粒子附加形成的表观活化能值。合金中Al3(Sc,Zr)相的析出动力学似乎与mn和mg的添加无关。经550℃退火后,电子背散射衍射观察到冷轧合金有部分再结晶。在550℃/30 min退火后,冷轧引起的显微硬度差异几乎消失。
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Mechanical, Thermal and Electrical Characteristics of Conventionally Cast and Cold-Rolled 5754-Sc-Zr Aluminium Alloy
The effect of cold-rolling on mechanical, thermal, and electrical properties as well as microstructure behaviour of the Al-2.93wt.%Mg-0.34wt.%Mn-0.33wt.%Si-0.22wt.%Fe-0.19wt.%Cr-0.24wt.%Sc-0.06wt.%Zr was studied. The material was investigated during step-by-step isochronal annealing in a temperature range from room temperature up to 540 °C and during isothermal annealing at 200, 450 and 550 °C. Precipitation reactions were studied by electrical resistometry, conductivity, (micro) hardness measurements and differential scanning calorimetry. The hardening effect appears due to the additional precipitation of the Al3Sc and/or Al3(Sc,Zr) particles. The distinct changes in residual resistivity ratio above ~ 330 °C are probably caused by precipitation of the Mn (,Fe,Cr)-containing particles. This precipitation process is highly influenced by cold rolling but it has a negligible effect on hardness. The apparent activation energy values for additional formation of the Al3Sc and/or Al3(Sc,Zr) particles were determined. The kinetics of the Al3(Sc,Zr)-phase precipitation seems to be independent of Mn-and Mg-addition in the studied alloys. A partial recrystallization of the cold-rolled alloy was registered by electron backscatter diffraction after annealing at 550 °C. The initial difference in microhardness introduced by cold rolling is almost removed after annealing at 550 °C/30 min.
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