一种利用红外光反馈腔增强光谱法检测微量气体的方案

Shiyu Guan, Huilin Cao, Yucheng Ouyang, Z. Tan
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摘要

腔增强吸收光谱(CEAS)技术是一种灵敏度高、检测原理相对简单的新型激光吸收光谱技术,在痕量气体检测领域发展迅速,越来越受到人们的欢迎。以超低膨胀系数玻璃陶瓷制成的优质光学无源谐振器为基础,结合半导体激光器的光反馈效应,建立了一种高灵敏度红外光反馈腔增强吸收光谱系统方案,该方案可以缩小输出激光线宽,稳定激光频率。系统的光谱扫描是通过同时扫描谐振腔腔长和调谐激光电流来实现的,光谱分辨率为0.003 cm-1,噪声等效吸收灵敏度优于2×10-9 cm-1Hz-1/2。该系统有望应用于呼吸气体的实时分析,实现该技术在人体呼吸诊断中的应用。
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A scheme for trace gas detection using infrared optical feedback cavity enhanced spectroscopy
Cavity enhanced absorption spectroscopy (CEAS) technology is one of the new types laser absorption spectroscopy technique with high sensitivity and relatively simple detection principle, which is developing rapidly and becoming more and more popular in the field of trace gas detection. A scheme of high sensitivity infrared optical feedback cavity enhanced absorption spectroscopy system is established, based on the high quality optical passive resonator made of ultralow expansion coefficient glass-ceramics, combined with the optical feedback effect of semiconductor laser which can narrow the output laser linewidth and stabilize the laser frequency. The spectral scanning of the system is realized by simultaneously scanning the cavity length of the resonator and tuning the laser current, and the spectral resolution of 0.003 cm-1 and the noise equivalent absorption sensitivity are better than 2×10-9 cm-1Hz-1/2. The system is expected to be applied to real-time analysis of respiratory gas and realize the application of the technology in human breath diagnosis.
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