资料报告:361考察队,西南印度洋纳塔尔山谷IODP站点U1474沉积物的x射线荧光岩心扫描

D. P. Babin, A. Franzese, S. Hemming, I. Hall, L. Levay, S. Barker, L. Tejeda, M. Simon
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引用次数: 1

摘要

x射线荧光(XRF)岩心扫描是对国际海洋发现计划地点U1474的岩心剖面进行的,该地点位于南非海岸附近的纳塔尔山谷。数据以2毫米的分辨率沿着255米的拼接长度收集,但这种设置导致数据有噪声。在将峰值面积转换为元素强度之前,通过对XRF数据应用10点运行和来解决这个问题。这有效地将10个测量值集成为1个,代表平均超过2厘米的分辨率,并显着改善数据中的噪声。使用电感耦合等离子体发射光谱法获得25个校准样品的元素浓度,并使用单变量对数比校准方法将XRF测量值转换为浓度。结果表明,陆源主要元素(Al、Si、K、Ti和Fe)的浓度与Ca浓度呈负相关关系,表明控制沉积物化学的主要因素是陆源与原位生成碳酸盐物质的比例变化。
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Data report: X-ray fluorescence core scanning of IODP Site U1474 sediments, Natal Valley, Southwest Indian Ocean, Expedition 361
X-ray fluorescence (XRF) core scanning was conducted on core sections from International Ocean Discovery Program Site U1474, located in the Natal Valley off the coast of South Africa. The data were collected at 2 mm resolution along the 255 m length of the splice, but this setting resulted in noisy data. This problem was addressed by applying a 10 point running sum on the XRF data prior to converting peak area to element intensities. This effectively integrates 10 measurements into 1, representing an average over 2 cm resolution, and significantly improves noise in the data. With 25 calibration samples, whose element concentrations were derived using inductively coupled plasma–optical emission spectrometry, the XRF measurements were converted to concentrations using a uni-variate log-ratio calibration method. The resulting concentrations of terrigenously derived major elements (Al, Si, K, Ti, and Fe) are anticorrelated with Ca concentrations, indicating the main control on sediment chemistry is the variable proportion of terrigenous to in situ produced carbonate material.
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Data report: evaluation of shipboard magnetostratigraphy by alternating field demagnetization of discrete samples, Expedition 361, Site U1475 Data report: X-ray fluorescence core scanning of IODP Site U1474 sediments, Natal Valley, Southwest Indian Ocean, Expedition 361
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