双模板法合成的二氧化硅呈红色并具有纹理介孔

G. Olvera-González, R. Nava-Mendoza, V. Hernández-Morales, C. Peza-Ledesma
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引用次数: 0

摘要

溶胶-凝胶法是用于合成具有双峰和分层孔隙结构的材料的技术之一,可以通过不同的表征技术来验证。采用扫描电镜(SEM)和氮气吸附-解吸等温线对多孔硅材料进行了表征,证实了表面活性剂的超分子模塑形成的二氧化硅颗粒内部存在直径在2 ~ 4nm范围内的介孔。此外,9-22 nm范围内的结构介孔是二氧化硅颗粒之间空隙的结果。此外,我们可以将这种类型的网状介孔与二氧化硅颗粒之间留下的空间或空隙产生的织构介孔区分开来,其范围在9-22 nm范围内。烷基胺表面活性剂和聚乙二醇表面活性剂分别用于控制颗粒的内部结构和聚集。
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Silica displaying red and textural mesoporosity sinthesized by double templating procedure
The Sol-Gel method is one of the techniques used to synthesize materials with a bimodal and hierarchical pore structure, which can be verified by different characterization techniques. The techniques of characterization of the materials of Silica exhibiting multimodal hierarchical porosity are Scanning Electron Microscopy (SEM) and Nitrogen adsorption-desorption isotherms, which serve to corroborate that there are mesopores with diameters in the 2–4 nm range in the internal part of the silica particles originated by the supramolecular molding by the surfactant. Furthermore, textural mesoporous in the 9–22 nm range are a result of voids between silica particles. In addition, we can distinguish this type of network mesoporosity from the textural mesoporosity originated by the spaces or voids left between the silica particles, which falls in the 9–22 nm range. The alkylammonium surfactants and Poly (ethylene glycol) have been used to control the internal structure and the aggregation of particles, respectively.
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