丝光和乙酰化对棕榈纤维硬度的影响

N. Obinichi, I. Uchegbulam
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摘要

随着对环保产品需求的增加以及全球对减少制造过程中毒性的意识的提高,需要更加密切地关注以植物为基础的原材料(如拉菲亚棕榈纤维)的开发。研究了在不同干燥温度和纤维长度下,氢氧化钠和乙酸酐浓度对棕榈纤维硬度的影响。以10%的氢氧化钠溶液和5%的乙酸酐为原料,丝光纤维干燥温度为70℃,乙酰化纤维干燥温度为50℃,纤维长度为50mm、60mm、70mm和80mm。结果表明,在10% NaOH(70℃)和5%乙酸酐(50℃)条件下,乙酰化纤维的硬度值分别为257HR和370HR,与丝光纤维相比,乙酰化纤维的洛氏硬度值提高了30.38%。值得注意的是,在理想纤维长度为60mm时,两种处理均获得了这些结果。因此,在5%的乙酸酐浓度和50℃的烘箱干燥温度下,以60mm的纤维长度进行乙酰化处理,可获得最佳的棕榈纤维硬度值。强烈建议在汽车、建筑、制造、医疗、体育、石油和天然气行业的复合材料工业商业化中使用。此外,本研究结果将为尼日利亚拉菲亚棕榈纤维作为潜在的增强材料在国内和国际市场和应用中开辟新的经济价值。
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Performance evaluation of mercerization and acetylation on hardness of raffia palm fibre
As the demand for environmentally friendly products rises and global awareness on reducing toxicities in manufacturing increases, the exploitation of  plant-based raw materials like raffia palm fiber requires closer attention. In this study, the effect of sodium hydroxide and acetic anhydride concentration  on the hardness of raffia palm fiber at varying drying temperature and fiber length were investigated. The treatments were carried out using 10% sodium  hydroxide solution and 5% acetic anhydride at oven drying temperatures of 70oC for mercerized fiber and 50oC for acetylated fiber with varying  fiber length of 50mm, 60mm, 70mm and 80mm. Findings show hardness values of 257HR and 370HR for 10% NaOH at 70oC and 5% acetic anhydride at  50oC respectively showing a 30.38% rise in Rockwell Hardness value in the acetylated fibers over the mercerized cohorts. Remarkably, these results were  obtained at ideal fiber lengths of 60mm in both treatments. Hence, acetylation treatment at 5% acetic anhydride concentration and 50oC oven-drying  temperature using 60mm fiber length offered optimal hardness value for raffia palm fiber. This is highly recommended for industrial commercialization  for composites in the automobile, construction, manufacturing, medical, sports, oil and gas industries. In addition, the results from this study will open  new economic values for Nigerian Raffia Palm fiber as potential reinforcement material for both domestic and international markets and applications. 
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