静压称重法测定IAPSO标准海水的密度

P. A. Giuliano Albo, S. Lago, R. Romeo
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摘要

在计量术语中,海水盐度仍然是海洋科学框架中使用的最有问题的量之一。主要原因是,尽管盐度有明确的定义,但该装置的实现仍然与使用以电导率测量为特征的自然来源的人工制品有关。后者似乎是目前唯一能够保证必要准确性的量。然而,盐度的概念,而不是定义,与海水中所含物质的数量有关,而海水不是纯水,电导率测量只能部分覆盖表征海水热力学行为的物理化学方面。在这些情况下,密度测量更为合适,并且由于其最近的进展,它似乎是一种有希望保证海水盐度测量可追溯性的方法。这项工作是对IAPSO标准海水密度测量的贡献,使用静水称重的方法。尽管这种方法仅限于在大气压下工作,但就精度而言,它是最好的方法。主要从计量学的角度对测量方法进行分析,重点关注支持所得结果可靠性的溯源链。
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Density measurements of IAPSO Standard Seawater by hydrostatic weighing
In metrological terms, salinity of seawater remains one of the most problematic quantity used in the frame of ocean science. The main reason is because, despite a clear definition of salinity, the realization of the unit is still linked to the use of artifact of natural origin characterized by measurements of conductivity. The latter seems to be the only quantity capable to guarantee the necessary accuracy at the moment. However, the concept of salinity, but not the definition, is linked to the quantity of substance contained in seawater, that is not pure water, and conductivity measurement can only partially cover the physico-chemical aspects characterizing the thermodynamic behavior of seawater. In these cases, the measurement of the density is more appropriate and, thanks to its recent progresses, it seems to be a promising way to guarantee the traceability of salinity measurement in seawater. This work is a contribution to the measurement of the density of IAPSO standard seawater, using the method of hydrostatic weighing. Despite this method is limited to work at atmospheric pressure, it is the best approach in term of accuracy. The measurement method is, mainly, analyzed from the metrological point of view, focusing on the traceability chain supporting the reliability of the obtained results.
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