木薯茎作为生物油潜在生物质的电磁催化液化特性研究

L. Lismeri, M. Anggraini, A. Sudarni, Y. Darni
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摘要

摘要生物质作为可再生能源生产生物油已被认为是满足未来能源需求的合适替代品。木薯茎作为作物残茬大量存在,是潜在的可利用生物质。作为原料,它具有生长快、容易、维护少、利用人工地不与粮食供应竞争等优点。生物量表征结果表明,木薯茎中纤维素、半纤维素和木质素含量分别为40.16、25.66和16.65% w/w。木薯茎具有低灰分、高挥发物、高碳低氮的特点。木薯茎的HHV为19.08 MJ/kg。采用气相色谱-质谱法对电催化液化(EA-CL)制备的生物油进行了物性分析,结果表明,生物油的主要化学成分为5-甲基糠醛、2-糠醛和乙酸。生物油密度范围为0.979 ~ 0.984 g/mL, pH值为2.8。这一结果表明,木薯茎是进一步生产生物油的合适原料。采用EA-CL工艺的生物油符合生物油标准。关键词:液化,生物质,生物油,气相色谱-质谱
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Characterization of Cassava Stems as Potential Biomass for Bio-Oil Production via Electromagnetic-Assisted Catalytic Liquefaction
ABSTRACTThe production of bio-oil from biomass as renewable sources has been trusted as a suitable alternative in supplying future energy needs. Present in abundance amounts as crop residues cassava stems is potential biomass tobe utilized. As raw material, it has advantages such as fast and easy growth, minimal maintenance and utilizing plantation land without competing with food supply. The biomass characterization results showed that cassava stems containing cellulose, hemicellulose and lignin, respectively 40.16, 25.66 and 16.65% w/w. Cassava stems has low ash content and high of volatile matter with high carbon and low nitrogen.The HHV of cassava stems was19.08 MJ/kg.Physical propertiesby GC-MS tests of bio-oil produced via electromagnetic-assisted catalytic liquefaction(EA-CL)revealedthat the dominant content of chemicals were 5-methyl furfural,2-furancarboxaldehyde and acetic acid.The bio-oil density ranged from 0.979 to 0.984 g/mL and has a pH of 2.8. This result shows that cassava stemis appropriate biomass for further bio-oil production feedstock.Bio-oil using EA-CL process meets bio-oil standards.Keywords:Liquefaction, Biomass, Biooil, GC-MS
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