混合叶片对燃料包壳内氢扩散和氢化物形成影响的评价

A. Aly, V. Petrov, M. Avramova, A. Manera, K. Ivanov
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摘要

燃料包层是裂变产物向环境释放的重要屏障。在反应堆寿命期间以及乏燃料池和干桶贮存期间,必须保持其完整性。在轻水堆中,锆基包层与水冷却剂之间的腐蚀相互作用导致了锆基包层的氧化。由于这些腐蚀性相互作用或水冷剂的辐射分解而释放的氢的一小部分被燃料包壳吸收。在浓度和温度梯度的驱动下,它在包层内部扩散。最终,它的浓度会增加到超过一定的限度,超过这个限度,氢就会以氢化物的形式析出。氢化物的形成会使熔覆层发生脆裂,并导致微裂纹,从而损害熔覆层的完整性。在间隔栅位置,混合叶片将产生涡流流和冷却剂的混合,导致燃料棒包壳上的高温梯度。这种温度梯度是氢从高温位置向低温位置扩散的强大驱动力。因此,氢气在带有混合叶片的间隔网格周围的行为对建模很重要。本文采用计算流体力学程序START-CCM+模拟混合叶片对包层外表面温度分布的影响。它与运输代码MPACT和燃料性能代码BISON相结合。计算模型由一个5 × 5的燃料棒组件组成,在中心位置有一个导流管。将得到的包层温度分布作为边界条件应用于BISON,以三维方式模拟间隔栅周围的氢行为。三个间隔网格分别在海拔217.9 cm、270.14 cm和322.35 cm处建模。对每个位置的氢行为进行评估和比较,以评估这些位置的重要顺序。
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Evaluation of the Mixing Vanes Effect on the Hydrogen Diffusion and Hydride Formation in the Fuel Cladding
The fuel cladding is an important barrier to the release of fission products to the environment. Its integrity must be conserved during the in-reactor lifetime and during the spent fuel pool and dry cask storage. The corrosive interaction between the cladding and the water coolant in light water reactors leads to the oxidation of the zirconium-based cladding. A fraction of the hydrogen released due to those corrosive interactions or the radiolysis of the water coolant is picked-up by the fuel cladding. It diffuses inside the cladding driven by the concentration and temperature gradients. Eventually, its concentration can increase beyond a certain limit above which hydrogen precipitates as hydrides. The formation of hydrides can embrittle the cladding and leads to micro-cracks that can compromise the cladding integrity. At the spacer grids locations, the mixing vanes will create swirl flow and mixing of the coolant leading to a high temperature gradient on the fuel rod cladding. This temperature gradient is a strong driving force for hydrogen to diffuse from high to low temperature locations. Therefore, the hydrogen behavior around the spacer grids with mixing vanes is important to model. In this work, the computational fluid dynamics code START-CCM+ is used to model the effect of the mixing vanes on the temperature profile on the cladding outer surface. It ws coupled with the transport code MPACT and the fuel performance code BISON. The computational model consisted of a 5 × 5 fuel rods subassembly with a guide tube in the central location. The obtained cladding temperature profile on a fuel rod of interest was applied as a boundary condition to BISON to model the hydrogen behavior around the spacer grids in a three-dimensional manner. Three spacer grids were modeled at elevations of 217.9 cm, 270.14 cm and 322.35 cm. The hydrogen behavior at each of those locations is evaluated and compared to assess the importance order of those locations.
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