不同温度下石墨烯在数字电极间微型超级电容器上生长的PECVD结构分析

H. E. Z. Abidin, A. A. Hamzah, M. A. Mohamed, J. Yunas, B. Majlis, M. Abid
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引用次数: 1

摘要

本文研究了在不同温度下等离子体增强化学气相沉积法(PECVD)生长石墨烯的平面数字间微型超级电容器。该微型超级电容器的结构由二氧化硅衬底、石墨烯生长在镍(Ni)电极上,涂有聚吡咯(Ppy)和聚乙烯醇(PVA)层作为固态电解质。具有sp2杂化碳原子的单层石墨烯具有高比表面积、高热导率和高电子迁移率等优点,是微超级电容器电极的重要材料之一。PECVD法具有生长选择性高、纳米结构图像化控制好等优点,是石墨烯生长的主要方法。在这项工作中,研究了石墨烯在400°C到1000°C的不同温度下在指间电极上的生长。利用拉曼光谱对微型超级电容器数字间电极上石墨烯的生长结构进行了表征。采用532 nm激光激发进行拉曼光谱分析。在数字间电极上观察了石墨烯的拉曼光谱,发现了D、G和2D三个峰。拉曼光谱显示,在1000℃时,二维带和G带的强度比为0.43,表明多层石墨烯生长质量良好。
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Structural analysis of graphene growth on interdigital electrodes micro supercapacitor by PECVD at various temperatures
Planar interdigital micro supercapacitor with the graphene growth via Plasma Enhanced Chemical Vapor Deposition (PECVD) with the different temperatures has been investigated in this works. The structure of the micro supercapacitor consists of SiO2 substrate, graphene growth on Nickel (Ni) electrodes coated with Polypyrrole (Ppy) and Polyvinyl Alcohol (PVA) layers as solid state electrolyte. A single layer of graphene which has sp2 hybridized carbon atoms is one of the promising material that has been used for micro supercapacitor electrodes due to several advantages such as high specific surface area, high thermal conductivity and high electron mobility. PECVD method is a main method for graphene growth due to the advantages such as high growth selectivity and good control in nanostructure patterning. In this works, the graphene growth on the interdigital electrodes was investigated in various temperatures from 400°C to 1000°C. The graphene growth structure on the interdigital electrodes of micro supercapacitor was characterized by Raman Spectroscopy. Raman Spectroscopy was carried out using a 532 nm laser excitation. A Raman spectrum of graphene was observed on interdigital electrode have identified three peaks which is D band, G band and 2D band. Raman spectra show that the intensity ratio of the 2D band and G band at 1000°C of 0.43 indicating a good quality of multilayer graphene growth.
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