酸性电解质中碳的电极电位

N. M. Winslow
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引用次数: 8

摘要

当碳在酸的存在下暴露于氧中时,它产生可测量的氧化特性,如氧化还原剂(如亚铁)的电位或能力。酸和氧的吸附对氧化性的发展是必不可少的。给出了几种碳的活性氧和电位与酸吸附的定量相关性,并给出了各种实验结果,表明碳表面活性配合物形成的可能化学机制。
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Electrode Potentials of Carbon in Acid Electrolytes
When carbon is exposed to oxygen in the presence of acid, it develops oxidizing characteristics measurable as potential or as capacity to oxidize reducing agents such as ferrous iron. Sorption of both acid and oxygen is essential to the development of oxidizing properties. Quantitative correlations of active oxygen and potential with acid sorption are given for several carbons, and the results of miscellaneous experiments indicating a possible chemical mechanism for the formation of active surface complexes on carbon are presented.
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