在各向异性晶体36XY-LiTaO3衬底上制备金纳米粒子的双带局域表面等离子体共振谱

Teguh Firmasnyah, G. Wibisono, E. Rahardjo, J. Kondoh
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摘要

局部表面等离子体共振是金属纳米粒子与特定波长的入射光高度相互作用时产生的效应。研究主要集中在改变MeNPs的大小、结构和形状以适应LSPR光谱效应。然后,通常通过修改MeNPs的配置来获得双峰/双频LSPR谱。然而,各向异性晶体衬底对LSPR谱的影响尚未得到充分的研究。本文提出了一种在各向异性晶体36XY-LiTaO3衬底上利用金纳米粒子(AuNPs)制备双频LSPR的新方法。采用时域有限差分法(FDTD)对等离子体电磁场模拟、原子力显微镜成像和LSPR光谱测量进行了综合评价。得到了双波段LSPR,下波段波长为500 nm,上波段波长为700 nm。仿真结果与实测结果吻合良好,验证了该方法的有效性。
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Dual-band localized surface plasmon resonance spectrum using gold nanoparticles fabricated on anisotropic crystalline 36XY-LiTaO3 substrate
Localized surface plasmon resonance is the effect when metallic nanoparticles (MeNPs) have highly interacted with incident light at a specific wavelength. Studies have focused on modifying the size, structure, and shape of MeNPs to the LSPR spectrum effect. Then, the dual-peak/dual-band LSPR spectrum was usually obtained using modify the configuration of MeNPs. However, the influences of the anisotropic crystalline substrate on the LSPR spectrum remain poorly explored. As a novelty, a dual-band LSPR using gold nanoparticles (AuNPs) was fabricated on the anisotropic crystalline 36XY-LiTaO3 substrate is proposed. Comprehensive evaluations were performed with finite-difference time-domain method (FDTD) simulation for plasmonic E-field simulation, atomic force microscopy imaging, and measurement of LSPR spectrum. As a result, the dual-band LSPR has obtained at a wavelength of 500 nm and 700 nm for the lower-band and upper band, respectively. A good agreement between simulation and measurement has validated the proposed method.
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