功能基团对牛大腿骨动物胶分子间引力的影响

T. Chikwe, R. Duru
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摘要

利用Shidmazu傅里叶变换红外(FT-IR) - 8300光谱对牛股骨样品中的官能团进行了测定。骨头被压碎,用温水适当清洗,并在石灰溶液中浸泡三天。然后用稀释20%的盐酸(以释放骨头中的胶原蛋白)处理样品,干燥并压碎至0.02毫米的粒度。FT-IR分析结果表明,在3550 ~ 3200 cm-1、2360 ~ 2014 cm-1、1420 ~ 1320 cm-1、1099 ~ 1039 cm-1、1970 ~ 890 cm-1和705 ~ 550 cm-1波长范围内分别存在醇、炔、羧酸、磷酸、1,3二取代芳烃和卤代烷。除了卤代烷中存在卤素和炔中存在多个键外,羧酸、酸酐和磷酸盐中还存在具有高电负性原子的官能团,如两个氧原子、三个氧原子和四个氧原子;丁腈和烯烃增加了化合物的极化性,从而增强了粘附分子的弱分子间引力,如氢键和范德华力,最终增加了所产生的动物胶的粘附强度和内聚力。
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Impacts of functional groups on the intermolecular forces of attraction in animal glue obtained from the femur bones of cow (Bos taurus)
Functional groups in samples obtained from the femur bone of Cow (Bos taurus) were determined using Shidmazu Fourier transform infrared (FT-IR) – 8300 spectroscopy. The bones were crushed, washed properly with warm water and immersed in lime solution for three days. Samples were then treated with dilute 20% hydrochloric acid (to release the collagen in the bone) dried and crushed to a particle size of 0.02 mm. Results obtained from FT-IR analyses shows the presence of alcohol, alkyne, carboxylic acid, phosphate, 1,3 disubstituted aromatics and haloalkanes at wavelength ranges of 3550 – 3200 cm-1, 2360 – 2014 cm-1, 1420 – 1320 cm-1, 1099 – 1039 cm-1, 970 – 890 cm-1 and 705 – 550 cm-1 respectively. The presence of functional groups with highly electronegative atoms such as two, three and four oxygen atoms in carboxylic acid, anhydrides and phosphates respectively in addition to the presence of halogens in haloalkanes and multiple bonds in alkyne, nitrile and alkenes increases the polarizability of the compounds thereby strengthening the weak intermolecular forces of attraction such as hydrogen bond and Van der Waal forces of the adhesive molecules which ultimately increases the adhesive strength and the force of cohesion of the animal glue produced.
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