基于改性三聚氰胺聚合物的新型高效增塑剂

I. Torresan, R. Khurana
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摘要

基于磺酸三聚氰胺甲醛凝聚聚合物(SM)的外加剂已经在商业上使用了三十多年。这些产品广泛应用于预制混凝土行业,但在坍落度保持和早期强度方面存在一定的局限性。为了改善这些性能,合成了一种改性的磺酸三聚氰胺甲醛凝聚聚合物(MSM)。本文报道了其理化特性。采用水泥浆体进行了分散性和吸附试验,比较了新型MSM聚合物与SM聚合物的超塑效果。通过与其他类型的高效减水剂(如SM和-萘磺酸甲醛冷凝物(SN))进行比较,对该MSM聚合物的性能进行了评价。试验结果表明,在试验条件下,与其他高效减水剂相比,MSM聚合物具有更好的减水能力、较低的新拌混凝土空气含量和较高的1天早期强度。这些特性是预制行业非常需要的,便于混凝土的放置和模板的快速翻转。现场测试也证实了实验室的发现。
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New Super-plasticizers Based on Modified Melamine Polymer
Admixtures based on sulfonate melamine formaldehyde condensate polymer (SM) have been available commercially for more than three decades. These products are widely used by the precast concrete industry, but with some limitations on slump retention and early strength. To improve these properties, synthesis of a modified sulfonate melamine formaldehyde condensate polymer (MSM) was performed. In this paper its physical and chemical characteristics are reported. Dispersibility and adsorption tests, using cement pastes, were carried out to compare the superplasticizing effect of the new MSM polymer against the SM polymer. Concrete mixtures were also made to evaluate the performances of this MSM polymer in comparison with the other types of superplasticizers such as SM and beta-naphthalene sulfonate formaldehyde condensate (SN). Results of these tests show that MSM polymer has a better water reduction capacity, lower air content in the fresh concrete and higher early strength at 1 day as compared to the other superplasticizers under the test conditions. These characteristics are very much desired by the precast industry for easy placement of concrete and quick turn around of the formworks. Field tests also reported, confirm the laboratory findings.
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