新型电绝缘材料——3D打印聚乳酸的光降解耐久性

O. Šefl, P. Veselý, Jaroslav Minář, K. Dušek
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引用次数: 1

摘要

由太阳辐射引起的塑料材料的降解限制了它们在室外应用的使用。因此,我们的目标是找到3D打印聚乳酸(PLA)的光降解与其电学和热力学性能之间的关系。在第一阶段,根据样品的介电强度对打印设置进行优化。然后,将打印的标本暴露在不同光谱和持续时间的紫外线下。采用光谱峰为254和385 nm的紫外气体放电灯作为强紫外光源;个体暴露时间分别为6、12、24、48和96小时。随后,对每组材料的介电强度进行了评估,并进行了热力学分析。254 nm辐照对聚乳酸的介电强度影响不大,但对聚乳酸的介电强度影响不大。尽管如此,两种紫外光源都造成了相当大的脆性,这可能是PLA户外应用的限制因素。
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Novel Electrical Insulation Materials – Photodegradation Endurance of 3D Printed Polylactic Acid
The degradation of plastic materials induced by solar radiation can limit their use in outdoor applications. Therefore, we aimed to find a relationship between the photodegradation of 3D printed polylactic acid (PLA) and its electrical and thermomechanical properties. In the first stage, the printing settings were optimized with regard to the dielectric strength of samples. Afterward, the sets of printed specimens were exposed to UV light of different spectrum and duration. UV gas-discharge lamps with spectral peaks at 254 and 385 nm were used as intense UV light sources; the individual exposure times were chosen as 6, 12, 24, 48, and 96 hours. Subsequently, the dielectric strength of each set was evaluated, and thermomechanical analyses were performed. Although the irradiation at 254 nm caused substantial degradation of PLA, it did not remarkably affect its dielectric strength. Nonetheless, both sources of UV light caused a considerable brittleness that might be the limiting factor for the outdoor application of PLA.
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