碳酸盐岩储层潜在危害因素测试与分析

X. Xia, Jianye Mou, Yongchun Zhang, Xiaoming Li, Yuelin Li
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摘要

目前对碳酸盐岩储层中注入水、压裂液和钻井液的污染损害研究较多,而潜在的产物沉淀损害研究较少。大牛地气田马家沟组主要有两种岩石样品,一种以白云岩为主,另一种以石膏为主。一方面,通过矿物组成分析,白云石样品的主要成分是CaCl2和MgCl2。然后对酸岩反应产物溶液中的离子浓度进行了测试,结果表明,四组中Ca2+含量最高和Mg2+含量最高的离子浓度低于Ca2+和Mg2+溶解度最低的离子浓度,因此产物不会达到过饱和状态而在溶液中沉淀。另一方面,对于以石膏为主的岩样,经水浸和酸溶液腐蚀后,岩板质量变化不大。然后对石膏样品进行酸驱,观察样品的表面形貌变化,并测量样品的质量变化。试验结果表明,样品的溶出量很小。因此,表明水和酸不会与石膏发生反应,不会产生潜在的沉淀。
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Testing and analysis of potential damage factors in carbonate reservoir
The pollution damage of injected water, fracturing fluid and drilling fluid in carbonate reservoir are mainly studied, however, the potential product precipitation damage have been seldom studied. Majiagou Formation in Daniudi gas field mainly has two kinds of rock samples, one with dolomite as the main component and the other with gypsum as the main component. On the one hand, through mineral composition analysis, the main composition of dolomite sample is CaCl2 and MgCl2. Then the ion concentration of acid rock reaction product solution was tested, the results show that the highest Ca2+ content and the highest Mg2+ content in the four groups are lower than the lowest solubility of Ca2+ and Mg2+, so the products will not reach supersaturated state and precipitate in the solution. On the other hand, for the rock sample dominated by gypsum, the quality of rock plate changes little after water immersion and acid solution corrosion. Then the gypsum samples were subjected to acid displacement, and the surface morphology changes of the samples were observed and the mass changes were measured. The test results showed that the dissolution amount of the samples was small. Therefore, it shows that water and acid will not react with gypsum and will not produce potential precipitation.
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