熔盐环境下900℃等离子喷涂Al2O3基复合涂层中TiO2的影响

Gurdeep Singh, K. Goyal, R. Goyal
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引用次数: 3

摘要

在熔盐环境(40wt %Na2SO4+60wt%V2O5)下,研究了不同Al2O3-TiO2涂层对ASTM-SA213-T-22钢900℃热腐蚀的影响。实验包括在马弗炉中900℃加热涂覆和未涂覆试样1小时,室温冷却20分钟,循环50次。采用目视检查、重量变化测量、x射线衍射技术和扫描电镜/能量分散x射线分析对腐蚀试样进行了分析。结果表明:由于TiO2的存在,涂层与基体金属SA213-T22的结合力较好,与涂层相比,未涂层的基体受腐蚀的影响更大,并且由于氧化铁(Fe2O3)的形成而增加了更多的质量。TiO2的存在提高了Al2O3涂层的耐高温强度和耐久性。
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Effect of TiO2 on Plasma Sprayed Al2O3 Based Composite Coatings at 900℃ in Molten Salt Environment
The present work investigates the effect of hot corrosion on ASTM-SA213-T-22 Steel with different coatings of Al2O3-TiO2 at 900℃ in molten salt environment (40wt %Na2SO4+60wt%V2O5). The experimentation consisted of 50 cycles of heating coated and uncoated specimens for 1 hour at 900℃ in muffle furnace and cooling for 20 minutes at ambient temperature. The corroded specimens were analyzed using visual examination, weight change measurement, X-ray diffraction technique and Scanning electron microscopy/Energy-disperse X-ray analysis. The results showed that the uncoated substrate had been more affected with corrosion and gained more mass due to formation of iron oxide (Fe2O3) as compared to coated substrate because of better adhesion of Al2O3 coating with base metal SA213-T22 due to presence of TiO2. The presence of TiO2 increased the strength and durability of Al2O3 coating to withstand with high temperatures.
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