利用氧化铟锡纳米晶须提高薄硅光伏电池的效率

Wei-Lun Chang, En-Ting Liu, Chia‐Hua Chang, P. Yu, Chien-Hung Wu
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摘要

薄晶圆基太阳能电池具有显著降低光伏成本的潜力。为了增加光吸收从而提高电池效率,光捕获在这种薄晶硅太阳能电池中尤为关键。本文研究了在硅表面添加氧化铟锡纳米晶须以提高硅光电器件的近红外吸光度。纳米晶须的有效折射率在1 ~ 1.3之间逐渐变化,起到阻抗匹配层的作用,有利于近红外的光传输。具有这种独特折射率特性的材料在自然界中是不容易得到的。结果表明,复合结构太阳能电池在900 ~ 1100nm宽波长范围内实现了量子效率的提高,这对发展先进的薄衬底硅太阳能电池至关重要。
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Efficiency enhancement of the thin-silicon photovoltaics using indium-tin-oxide nanowhiskers
Thin wafer-based solar cells have the potential to significantly decrease the cost of photovoltaics. Light trapping is particularly critical in such thin-wafer crystalline silicon solar cells in order to increase light absorption and hence cell efficiency. In this article we investigate the indium-tin-oxide nanowhisker on textured silicon surface for enhancing the near-infrared absorbance of silicon photovoltaics. The nanowhiskers facilitate optical transmission in the near-infrared by functioning as impedance matching layers with effective refractive indices gradually varying from 1 to 1.3. Materials with such unique refractive index characteristics are not readily available in nature. As a result, the solar cell with combined textures achieves quantum efficiencies enhancement for a broad wavelength range of 900 to 1100 nm, which is crucial to the development of advanced thin-substrate silicon solar cells.
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