光伏应用中硅基钛钒氧化物的表征

K. Sieradzka, D. Kaczmarek, J. Domaradzki, E. Prociów, T. Berlicki
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引用次数: 0

摘要

目前的工作是关于异质结由透明氧化物半导体(TOSs)沉积在不同的硅(Si)衬底上,用于光伏电池。采用高能反应磁控溅射(HE RMS)制备了TOS-Si异质结。在钛靶上用V金属箔进行了溅射。选择钛钒混合氧化物作为TOS材料。纳米晶钛钒薄膜具有高透射系数(可见光谱范围约为76%),室温电阻率105¿cm和n型导电性。此外,沉积在Si衬底上的TOS薄膜通过降低纯Si薄膜的反射系数来实现增透功能。通过对不同TOS-Si异质结的电流电压比(I-V)测量,发现在有源辐射的影响下存在光电效应。因此,本文讨论了混合钛钒氧化物在各种光伏应用中的适用性。
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Characterization of titanium-vanadium oxides deposited on silicon substrates using in photovoltaic applications
The current work is concerned with heterojunctions consist of transparent oxide semiconductors (TOSs) deposited on different silicon (Si) substrates using in photovoltaics. The TOS-Si heterojunctions were fabricated by high energy reactive magnetron sputtering (HE RMS). The sputtering was performed from V metallic foils located on Ti target. As a TOS materials the mixed titanium-vanadium (Ti-V) oxides have been selected. The nanocrystalline titanium-vanadium thin films have high transmission coefficient (ca. 76 % in visible spectral range), resistivity 105 ¿cm at room temperature and n-type electrical conduction. Additionally, the TOS films deposited on Si substrate perform a antireflection function through reduce reflection coefficient of pure Si ones. Based on current to voltage (I-V) measurements of different TOS-Si heterojunctions, the existence of a photoelectric effect under the influence of active area radiation has been found. Therefore, the applicability of mixed titanium-vanadium oxides to various photovoltaics application has been discussed.
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