{"title":"气相色谱中的线形。3制备柱中的溶质-溶质相互作用","authors":"D. Wilson","doi":"10.1080/01496398708057615","DOIUrl":null,"url":null,"abstract":"Abstract The effects of solute-solute interactions on the shapes of the bands in preparative gas chromatography are modeled by numerical integration of the coupled sets of differential equations describing solute movement An asymmetrical upwind algorithm is used to describe advection; this greatly reduces the numerical dispersion which is inherent in the theoretical plate method. A microcomputer was used for doing the computations.","PeriodicalId":184327,"journal":{"name":"Preparative-Scale Chromatography","volume":"43 2 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1987-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Line Shapes in Gas Chromatography. III. Solute-Solute Interactions in Preparative Columns\",\"authors\":\"D. Wilson\",\"doi\":\"10.1080/01496398708057615\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The effects of solute-solute interactions on the shapes of the bands in preparative gas chromatography are modeled by numerical integration of the coupled sets of differential equations describing solute movement An asymmetrical upwind algorithm is used to describe advection; this greatly reduces the numerical dispersion which is inherent in the theoretical plate method. A microcomputer was used for doing the computations.\",\"PeriodicalId\":184327,\"journal\":{\"name\":\"Preparative-Scale Chromatography\",\"volume\":\"43 2 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1987-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Preparative-Scale Chromatography\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/01496398708057615\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Preparative-Scale Chromatography","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/01496398708057615","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Line Shapes in Gas Chromatography. III. Solute-Solute Interactions in Preparative Columns
Abstract The effects of solute-solute interactions on the shapes of the bands in preparative gas chromatography are modeled by numerical integration of the coupled sets of differential equations describing solute movement An asymmetrical upwind algorithm is used to describe advection; this greatly reduces the numerical dispersion which is inherent in the theoretical plate method. A microcomputer was used for doing the computations.