加速气候老化对玻璃纤维增强热固性复合材料体积和表面电阻率的影响

P. Prosr, R. Polanský, J. Pihera, P. Kadlec, M. Hirman, Tereza Krejnická, O. Musil, J. Komarek, R. Pavlica
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引用次数: 2

摘要

本文重点分析了在选定的加速气候老化条件下,选定的介电参数的稳定性。对不同热固性基体的玻璃纤维增强复合材料的稳定性进行了分析,该复合材料适用于电气绝缘材料和建筑构件的生产。选择不同类型的热固性树脂(环氧树脂和聚氨酯树脂)制备复合材料,这是本实验的主题。测试的复合材料首先在交付状态下进行表征,然后在加速气候老化后进行表征。计算了重要的介电参数,即体积电阻率和表面电阻率。实现了两种不同的加速气候老化试验。第一个是温湿度循环试验,包括(i)在温度55℃、湿度93% RH和(ii)在温度25℃、湿度97.5% RH下的交替间隔。二是湿热稳态试验,样品在温度85℃,湿度85% RH的条件下连续暴露1000小时。根据电阻率的测量数据,选择了有前途的材料进行进一步的活动,从而生产出具有良好电绝缘性能的建筑元件,并且受模拟气候条件的影响最小。
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Effects of Accelerated Climatic Aging on Volume and Surface Resistivity of Glass Fiber Reinforced Thermoset Composites
This paper is focused on the analysis of selected dielectric parameters stability under the conditions of selected accelerated climatic aging. This stability is analyzed for glass fiber reinforced composites with different thermosetting matrix suitable for the production of electrical insulating and also construction elements. Different types of thermosetting resins (epoxy and polyurethane resins) were chosen for the preparation of composites, which are the subject of the presented experiment. Tested composites were firstly characterized in the delivered state and then after the accelerated climatic aging. Important dielectric parameters were evaluated, which are the volume resistivity and the surface resistivity. Two different tests of accelerated climatic aging were realized. The first one was Temperature/humidity cyclic test, which consists of alternated intervals (i) under the temperature of 55 °C and the humidity of 93 %RH and (ii) under the temperature of 25 °C and the humidity of 97.5 %RH. The second one was Damp heat steady state test when samples were exposed to the temperature of 85 °C and the humidity of 85 %RH continuously for 1000 hours. Based on the measured data of resistivities, prospective materials were selected for further activities leading to the production of construction elements with also good electrical insulating properties and with their minimal affection by simulated climatic conditions.
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