蛋壳法制备羟基磷灰石/ZnO复合材料的研究进展

LA CONTRERAS-DE, M. Cruz, GARCÍA-GONZÁLEZ N †´´, ENRÍQUEZ-PÉREZ ´´, Ma Ángeles´
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摘要

本文提出了一种羟基磷灰石(HAp)/氧化锌(ZnO)基复合材料的合成和表征方法。蛋壳(ES)作为羟基磷灰石的来源。我们试图利用这两种材料的光催化活性。该复合材料可用于废水中有机染料的矿化。复合材料的制备方法是采用溶胶-凝胶法制备前驱体ZnO,将其与之前合成的羟基磷灰石混合,在650℃下煅烧。随后,使用拉曼光谱和x射线衍射(XRD)对所有材料进行表征,以确定存在的晶相;扫描电子显微镜(SEM)获得形貌;能量色散光谱(EDS)测定元素组成。合成HAp/ZnO复合材料是可能的,表征表明得到的是b型碳化羟基磷灰石复合材料。需要强调的是,复合材料的合成方法,并不是均相合成,建议寻找另一种浸渍方法。
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Preparation advances of hydroxyapatite/ZnO composite using egg-shell
In the present work, synthesis and characterization of a Hydroxyapatite (HAp)/Zinc Oxide (ZnO)-based composite in proposed. The Egg-shell (ES) is used as Hydroxyapatite source. We pretend to take advantage of photocatalytic activity of both materials. This composite can be applied in mineralization of organic dyes in waste water. The methodology followed for the preparation of the composite was carry out a Sol-gel of precursor ZnO synthesis, after, it was mixed with the previously synthesized Hydroxyapatite and calcinated at 650 °C. Later, all materials were characterized using of Raman Spectroscopy and X-Ray Diffraction (XRD), to determine the crystalline phases present; Scanning Electron Microscopy (SEM) to obtain the morphology; Energy Dispersive Spectroscopy (EDS) to determine elemental composition. It was possible to synthesize a HAp/ZnO composite, the characterization showed that it was obtained a composite with carbonated hydroxyapatite Type B. It is important to highlight that the method of composite synthesis, it was not a homogeneous synthesis, it is proposed to look for another impregnation method.
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