使用d -柠檬烯作为柴油-生物柴油混合物添加剂对压缩点火发动机废气组成的影响

D. Módolo, L. Pereira, L. Micheli
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引用次数: 2

摘要

植物油的酯交换反应产生脂肪酸甲酯,即生物柴油。它具有与柴油相似的特性,如十六烷值、比重、燃烧热和空燃比。然而,它的高粘度引起的问题导致喷油器的喷射效果差,从而导致低等级燃烧,导致发动机内部形成不良沉积物,改变润滑油的性质和废气的成分。因此,有必要研究一种能够使生物柴油的特性更适合于压缩点火发动机的添加剂,以及监测废气成分变化的添加剂。所选择的添加剂是d-柠檬烯,一种单环萜烯,作为柑橘的副产物。本文介绍了用不同浓度的柴油-生物柴油和d-柠檬烯混合燃料在固定式柴油机上进行的试验的初步结果,并与普通柴油进行了比较。虽然在低浓度下使用,但添加剂在减少碳氢化合物、一氧化碳和不透明度方面是有效的。
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EFFECTS OF THE USE OF D-LIMONENE AS AN ADDITIVE TO DIESEL-BIODIESEL BLENDS ON EXHAUST GASES COMPOSITION OF COMPRESSION IGNITION ENGINES
The transesterification of vegetable oils results in methyl esters of fatty acid, known as biodiesel. This one presents similar features of diesel oil, such as cetane number, specific weight, heat of combustion and air-fuel ratio. However, arising problems from its higher viscosity leads to a poor spraying by the fuel injectors and so to a low-grade combustion, causing formation of undesirable deposits inside the engine, changes in the properties of the lubricating oil and in the composition of the exhaust gas. Owing to this issue, it is necessary to study an additive able to make biodiesel characteristics more appropriate to be used in compression ignition engines, as well as a monitoring of changes in exhaust gas composition. The chosen additive was d-limonene, a monocyclic terpene obtained as a byproduct of citriculture. This paper presents the preliminary results obtained from the tests in a stationary diesel engine fuelled with mixtures of diesel-biodiesel and d-limonene, in different concentrations, comparing to regular diesel fuel. Although it was used in low concentrations, the additive was efficient in the reduction of hydrocarbons, carbon monoxide and opacity.
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