废纸污泥灰作为水泥替代砂浆支撑绿色技术材料的性能研究

Mohd Syahrul Hisyam bin Mohd Sani, Fadhluhartini bt Muftah, Marzuki Ab Rahman
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引用次数: 14

摘要

废纸污泥灰(WPSA)是从造纸工业中收集的废弃物。用WPSA代替水泥生产砂浆,对其化学、物理和力学性能进行了研究。建筑材料的自然资源现在变得有限,并造成空气污染和环境问题。由于硫酸盐含量较低,仅占总重量的0.57%,因此WPSA成为一种新的创新材料,可以用作砌筑材料,以支持绿色技术。由于水泥产量降低,二氧化碳和二氧化硫的排放也可以减少。通过与普通硅酸盐水泥(OPC)的对比,确定了WPSA的化学和物理性能。试验结果表明,WPSA与OPC的化学性能相近,砂浆的吸水率为27.05%。然而,SiO2、Al2O3和Fe2O3的三种组合的总百分比为45%,预计具有较低的火山灰反应性(50%)。WPSA分别用于50%、60%、70%、80%、90%和100%配比的砂浆中,与一定量的砂和水按体积替代水泥。另外还制备了一种不含WPSA的对照砂浆。在试验第3、7、28、60天分别测定各砂浆的抗压强度。结果表明:混凝土的抗压强度随养护龄期的增加而增大,随砂浆中WPSA的增加而减小;掺加50% WPSA可获得16.4 MPa强度较好的砂浆。同时,经济环保砂浆可采用70%和100%替代,分别适合12.5 MPa和7.7 MPa的低强度砂浆施工。
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Properties of Waste Paper Sludge Ash (WPSA) as cement replacement in mortar to support green technology material
Waste Paper Sludge Ash (WPSA) is a waste material collected from the Paper Industry. WPSA is used as cement replacement in producing mortar and was investigated on its chemical, physical and mechanical properties. Construction material with natural resources now become limited and causes of air pollution and environmental problems. WPSA becomes a new innovation material that can be used as material for masonry to support the green technology due to less presence of sulphate at only 0.57% of the total weight. Carbon dioxide (CO2) and Sulphur dioxide emission also can be reduced since less cement productivity is involved. The chemical and physical properties of the WPSA were determined by comparing it with the Ordinary Portland Cement (OPC). As the result of testing, it shows that WPSA is similar to the chemical properties of OPC and the water absorption of the mortar is 27.05%. However the total percentage of the three combinations of SiO2, Al2O3 and Fe2O3 was 45% and expected to possess low pozzolanic reactivity (50%). WPSA was used in mortar with proportions of 50%, 60%, 70%, 80%, 90% and 100% as cement replacement by volume along with sand and water in fix quantity. An additional control mix mortar without WPSA was also prepared. The compressive strength of each mortar mix was also determined on 3, 7, 28 and 60 days. Results show that the compressive strength increased with increasing curing age for all concrete mixes and the compressive strength decreases with increasing WPSA in the mortar. The inclusion of 50% WPSA can gain favorable strength mortar at 16.4 MPa. Meanwhile 70% and 100% replacement can be adopted for economical environmental mortar to suit lower strength mortar construction at 12.5 MPa and 7.7 MPa respectively.
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