利用微波技术可持续回收废环氧树脂、生物质及其共混物作为赤铁矿替代还原剂

Ernest Vijay Oteng, J. R. Dankwah
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引用次数: 0

摘要

循环经济要求产品被重复使用、回收或再生产成另一种产品,以实现可持续的环境。大气中温室气体的增加要求在生产中使用清洁燃料。众所周知,生物质含有相当数量的碳,同样,环氧树脂是一种热固性塑料。在1400w额定功率的家用微波炉上,用废环氧树脂、竹椰壳(CNS)作为还原剂对试剂级氧化铁(96.89 wt. % Fe2O3)进行了实验室研究。由氧化铁和碳质材料的混合物分别制成30%和70%的复合球团。复合颗粒在微波炉中加热30分钟。然后计算燃烧后的质量损失百分比和还原程度。结果表明,环氧树脂、竹材、CNS及其共混还原剂可有效地制备金属铁。结果表明,35%竹材、35% CNS和30%环氧树脂的共混物的还原率最高,为95.41%,其次是30%环氧树脂和70% CNS的共混物,还原率为92.92%。竹材、CNS和环氧树脂的碳质材料分别减少了74.76%、78.22%和83.65%。从实验室获得的结果来看,废环氧树脂、椰子壳和竹子可以作为氧化铁的替代还原剂,以环保和可持续的方式回收利用。此外,在微波环境中减少所取得的成功可以促进铁生产中使用的传统高炉的逐渐转变。
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Sustainable Recycling of Waste Epoxy, Biomass and Its Blends as Alternative Reductants for Hematite Using Microwave Technology
The circular economy demands that products are reused, recycled or reproduced into another product for a sustainable environment. The rising amount of greenhouse gases in the atmosphere calls for clean fuels to be used in production. Biomass is known to contain a considerable amount of carbon likewise, epoxy which is a thermosetting plastic. Laboratory studies on the use of waste epoxy, bamboo and coconut shells (CNS) as reductants were performed on reagent grade ferric oxide (96.89 wt. % Fe2O3) using a domestic microwave oven of 1400 W power rating. Composite pellets of 30% and 70% were formed from the mixtures of ferric oxide and carbonaceous materials respectively. The composite pellets were fired in a microwave oven for 30 minutes. The percent mass loss and extent of reduction were then calculated after firing. The results depict that metallic iron can be produced effectively using epoxy, bamboo, CNS and their blends as reducing agents. Analysis of the results indicates a blend of 35 % Bamboo, 35 % CNS and 30 % epoxy attained the highest reduction of 95.41 %, which was closely followed by a blend 30 % epoxy and 70 % CNS of 92.92 %. The individual carbonaceous materials also recorded significant reduction of 74.76 %, 78.22 % and 83.65 % for bamboo, CNS, and epoxy respectively. From the laboratory results obtained, waste epoxy, coconut shells and bamboo can be recycled in an eco-friendly and sustainable manner through their usage as an alternative reductant for ferric oxide. Also, the success achieved with reduction in the microwave environment can catalyse the gradual shift from the conventional blast furnace used in iron production.
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