含羞草生物炭吸附水溶液中亚甲基蓝的研究

N. X. Cuong
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引用次数: 2

摘要

研究了含羞草生物炭去除水溶液中的亚甲基蓝(MB)。利用傅里叶变换红外、扫描电镜和布鲁诺尔-埃米特-泰勒等方法测定了生物炭的性质。在500℃热解条件下,生物炭的产率达到24.62%。所得生物炭比表面积为285.53 m2/g,总孔径为0.153 cm3/g,灰分含量为2.79%。生物炭去除MB的最佳剂量为5 g/L,最佳pH为2 ~ 10。MB去除率在前30 min达到80%以上,随后在120 ~ 360 min的稳定时期达到90%以上。在25℃时吸附量达到20.18 mg/g。MB吸附数据符合动力学模型的顺序为:Avrami > Elovich > PSO > PFO。吸附过程可分为物理吸附、化学吸附和多阶段吸附。
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Study on Adsorption of Methylene Blue from Aqueous Solution by Biochar Derived from Mimosa Pigra Plant
Biochar from mimosa pigra was studied to remove methylene blue (MB) from aqueous solution. The properties of biochars were determined using Fourier Transform Infrared, scanning electron microscope, and Brunauer–Emmett–Teller. The biochar achieved the yield of 24.62 % at 500 oC pyrolysis. The specific surface area of ​​the biochar is 285.53 m2/g, the total pore size is 0.153 cm3/g and the ash content is 2.79%. The optimal dose of removing MB of the biochar is 5 g/L and the optimal pH is 2 - 10. MB removal reached over 80% in the first 30 min, followed by a stable period of 120 to 360 min reaching over 90% of removal. Maximum adsorption capacity reached 20.18 mg/g at 25 oC. MB adsorption data is suitable for kinetic models in order: Avrami > Elovich > PSO > PFO. The adsorption process may comprise physical and chemical adsorption andmultiple stages.  
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