基于分子模拟和实验对比的绝缘油溶解气体压力影响分析

Yiming Wu, Yuandi Lin, Peng Wu, Jiangang Xu, Tianxi Xie, Chenyu Gao, J. Hao
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摘要

变压器的密封性能对其安全运行有重要影响。然而,设备的密封性与所施加的压力有关。本文对矿物油进行了不同压力下的含气量测试,模拟了不同密封程度下的情况,并采用双参数威布尔分布对数据进行了分析。建立了矿物油与空气的复合模型,并在不同压力下进行了平衡。计算了矿物油中气体分子的含量以及气体分子与矿物油的相互作用。试验结果表明,矿物油的含气量随着压力的增大而逐渐增大。当压力由6.3kPa增加到101.3kPa时,矿物油中含气量以63.2%的概率由4.26%增加到8.99%。当压力增加16.08倍时,矿物油中气体含量增加2.11倍。三次测量结果重复性好。仿真结果表明,随着压力的增大,矿物油与气体分子之间的相互作用能逐渐增大,进入矿物油的气体分子数量增加。当压力由10.1kPa增加到1013kPa时,矿物油与气体分子的相互作用能由68.61 kcal/mol增加到104.98 kcal/mol。进入矿物油的气体分子数从110增加到161。实验结果与仿真结果吻合较好。
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Pressure Influence Analysis of Dissolved Gas in Insulation Oil Based on Molecular Simulation and Experimental Comparsion
The sealing performance of transformer has important influence on its safe operation. However, sealing of the equipment is related to the pressure that applied. In this paper, gas content test of mineral oil under different pressures were conducted to simulate the situation under different sealing degree, and the two-parameter Weibull distribution was used to analysis the data. Composite model of mineral oil and air have been built and balanced under different pressures. The amount of gas molecules in mineral oil and the interaction between gas molecules and mineral oil were calculated. The test results show that the gas content of mineral oil increases gradually with the increase of pressure. When the pressure increased from 6.3kPa to 101.3kPa, the gas content in mineral oil with a probability of 63.2 % increased from 4.26 % to 8.99 %. When the pressure increased by 16.08 times, the gas content in mineral oil increased by 2.11 times. The repeatability of the three measurements was good. The simulation results show that with the increase of pressure, the interaction energy between mineral oil and gas molecules increases gradually, and the number of gas molecules entering mineral oil increases. When the pressure increases from 10.1kPa to 1013kPa, the interaction energy between mineral oil and gas molecules increases from 68.61 kcal/mol to 104.98 kcal/mol. The number of gas molecules entering the mineral oil increased from 110 to 161. The experimental results are in good agreement with the simulation results.
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