头孢地尼衍生物席夫碱配合物的制备及物性研究

Haneen R. Ali, S. S. Hassan
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引用次数: 0

摘要

合成了头孢地尼C14H13N5O5S2衍生物(L)的Co、Ni、Cu、Zn金属(II)配合物,并通过元素分析CHNS Uv-Vis、FTIR、TGA、金属分析AA、磁化率和导电性测定进行了鉴定。经分析,该配体表现为双齿体。对于钴配合物,建议采用四面体几何形状,而镍、铜和锌离子配合物则建议采用八面体几何形状。研究了一种新型头孢地尼衍生物在3.5% NaCl溶液中对碳钢进行防腐的实验方法。结果表明,金属配合物在氯化钠溶液中对碳钢具有较强的耐蚀性,由于新型头孢地尼衍生物药物金属配合物从盐水溶液中吸附在碳钢表面,其缓蚀效率(%)随药物浓度的增加而增加。
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PREPARATION AND STUDY OF THE PHYSICAL PROPERTIES OF SOME COMPLEXES WITH SCHIFF BASE LIGAND FOR CEFDINIR DERIVATIVE
Metal (II) complexes of Co, Ni, Cu and Zn with cefdinir C14H13N5O5S2 derivative (L) were synthesized and identification by elemental analysis CHNS Uv-Vis, FTIR, TGA, metal analysis AA, magnetic susceptibility and conduct metric measurement. by analysis the ligand behaves as a bidentate. For the cobalt complex, Tetrahedral geometry shape was suggested, while other complexes that have nickel, copper and zinc ions were proposed as octahedral geometry shape. The experimental method was studied for prevention of corrosion carbon steel in 3.5% NaCl by using a novel Cefdinir derivations drugs. The results showed that metal complex was a strong corrosion resistance protect for carbon steel in sodium chloride and the inhibition efficiency (%) increased with increasing concentration of drugs due to that the novel Cefdinir derivative drugs metal complex was adsorpd from saline solution on surface of carbon steel.
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