生物质基高分子材料的生物降解性及其风险评估

Song-Yi Han, Chan-Woo Park, Jae-Hyuk Jang, Seung Hwan Lee
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摘要

为解决石油资源合成塑料带来的环境问题,以木材、麦麸等生物质为原料,采用液化法制备了可生物降解的聚氨酯泡沫塑料和热固性塑料。研究了这些生物质基高分子材料的生物降解性。在活性污泥中,液化麦麸制成的聚氨酯泡沫和酚醛化木材制成的热固性模塑分别在20天内分解约14%和29%。其中一种木真菌,花斑革菌(Coriolus versicolor)可以在没有补充营养的情况下生长,只需要蒸馏水和聚氨酯泡沫作为营养来源。风险评估也进行了,结果表明,在生物基高分子材料的提取物中没有观察到雌激素,诱变性和致癌性。
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Biodegradability and Risk Assessment of Biomass-based Polymeric Materials
With the intention to solve environmental problems caused by synthetic plastics from petroleum resources, biodegradable polyurethane foams and thermosetting moldings were prepared from biomass, such as wood and wheat bran by liquefaction method. Biodegradability of these biomass-based polymeric materials was investigated. In activated sludge, polyurethane foams from liquefied wheat bran and thermosetting molding from phenolated wood were decomposed approximately 14% and 29% for 20 days, respectively. One of the wood fungi, Coriolus versicolor was able to grow without supplemental nutrition, only with distilled water and polyurethane foam as a nutrition source. Risk assessments were also conducted and results showed that estrogenicity, mutagenicity, and carcinogenicity were not observed in the extractives of bio-mass-based polymeric materials.
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