基于TiO2薄膜的连续离子层吸附反应(SILAR)技术制备CdS量子点敏化太阳能电池及表征

H. Musleh, S. Shaat, N. Dahoudi, J. Asad, Samy Mansy
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摘要

量子点敏化太阳能电池是传统硅太阳能电池最实惠的替代品。II-VI半导体化合物作为量子点吸收剂已被广泛应用。在FTO层上沉积TiO2阻断层薄膜,防止电荷的复合,从而提高效率。制备了一种基于TiO2纳米结构的硫化镉量子点敏感太阳能电池。利用SILAR(连续离子层吸附和反应)方法降解TiO2薄膜。增强电传导和减少层间电荷的复合是表征光伏器件的一个非常有力的工具。将TiO2薄膜浸入0。05M KC1溶液在70℃下不同时间。利用电流-电压(I-V)对效率进行了实验测试,以提取制备的器件性能。硫化镉量子点太阳能电池的性能为1.5-1.82%。在AM1.5照度下,短路电流密度为5.922 mA/c$\ mathm {m}^{2}$,开路电压约为0.613 V。
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Fabrication and Characterization of CdS Quantum Dot-Sensitized Solar Cell Based on TiO2 Film by Successive Ionic Layer Adsorption and Reaction (SILAR) Technique
The most affordable alternatives to traditional silicon solar cells are quantum dot-sensitized solar cells. II-VI semiconductors compound have been widely used as Quantum Dot absorbers. Thin film of TiO2 blocking layer was deposited onto FTO layer to prevent recombination of charges to achieve higher efficiency. A TiO2 nanostructure-based cadmium sulfide quantum dot sensitive solar cell has been created. TiO2 films degrade utilizing the SILAR method (Successive Ionic Layer Adsorption and Reaction). Enhancement the electrical conduction and reducing the recombination of charges between layer is a very strong tool for the characterization of photovoltaic devices. TiO2 films were immersed into 0. 05M KC1 solution at 70 0C for different time. Efficiency was experimentally tested using current-voltage (I-V) in order to extract fabricated device properties. Solar cells with cadmium sulfide quantum dots are demonstrating a performance of 1.5-1.82%. Under AM1.5 illumination, a short circuit current density of 5.922 mA/c$\mathrm{m}^{2}$ and an open circuit voltage of around 0.613 V were attained.
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