摩尔浓度对MgO薄膜性能的影响

H. Zulkefle, L. N. Ismail, R. Abu Bakar, M. Mahmood
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引用次数: 10

摘要

氧化镁(MgO)是一种具有宽禁带(7.8eV)的无机材料,适合用作介电层。由于其化学和结构特性,MgO还可以作为模板制备铁电薄膜[1-3]。本文采用溶胶-凝胶自旋镀膜技术制备了0.1M ~ 1M不同摩尔浓度的MgO薄膜。四水乙酸镁、乙醇和硝酸分别作为前驱体、溶剂和稳定剂。将MgO薄膜沉积在玻璃衬底上,并进行电学和结构表征。电学和结构表征分别使用两个点探针(BUKOH KEIKI-EP2000),表面轮廓仪(Veeco)和原子力显微镜进行。实验结果表明,薄膜的电阻率从5.09开始增大×103 Ω。厘米到2.33 ×104 Ω。Cm随着前驱体摩尔浓度的增加而增大。0.4M的MgO薄膜具有均匀、无孔、粒径小等特点,是最适合用作介质层的MgO薄膜。
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Molar concentration effect on MgO thin films properties
Magnesium Oxide, MgO is inorganic material with wide band gap (7.8eV) and suitable to be used as dielectric layer. Due to its chemical and structural properties, MgO also can be used as template to prepare ferroelectric thin film [1–3]. In this work, MgO thin films with different molar concentration from 0.1M to 1M were prepared using sol-gel spin coating technique. Magnesium acetate tetrahydrate, ethanol and nitric acid were used as precursor, solvent and stabilizer respectively. The MgO thin films were deposited on the glass substrate and subjected to electrical and structural characterizations. Both electrical and structural characterizations were performed using two point probes (BUKOH KEIKI-EP2000), surface profiler (Veeco) and atomic force microscope respectively. The experimental results show that the thin films resistivity increased from 5.09 ×103 Ω.cm to 2.33 ×104 Ω.cm as the precursor molar concentration increased. The MgO films with 0.4M was observed to be the best MgO films to be used as dielectric layer due to its electrical and structural properties which are uniform, non-porous and small particle size around 43nm.
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