脉冲激光烧蚀法制备氧化锌纳米粒子光催化剂在水污染中的抗菌作用

Fatkhiyatus Sa’adah, Rizka Zakiyatul Miskiyah, A. Khumaeni
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引用次数: 1

摘要

采用脉冲激光烧蚀法制备了氧化锌纳米颗粒。以5 Hz、10 Hz和15 Hz脉冲激光为重复频率,在水介质中合成棕色胶体。激光重复率越高,胶体颜色就越呈深褐色。氧化锌纳米颗粒的表征包括UV-Vis, SEM-EDX, FTIR和XRD。SEM图像显示氧化锌纳米颗粒呈圆形。利用imageJ软件对扫描电镜图像的颗粒分布进行了测量,结果表明,在5 Hz、10 Hz和15 Hz下,ZnO纳米颗粒分别为23.63 nm、12.13 nm和5.59 nm。EDX光谱分析结果表明,ZnO纳米胶体中只合成了Zn和O原子。FTIR结果表明,在波数457 cm-1和545 cm-1处形成了链状ZnO。XRD分析结果还显示出一些称为ZnO相的峰。这表明ZnO纳米颗粒已经形成。采用液体稀释法测试ZnO纳米颗粒的抗菌活性,纳米颗粒浓度为40 ppm、60 ppm和80 ppm。试验结果表明,在浓度为40 ppm、60 ppm和80 ppm时,大肠杆菌的降解率分别为89.60%、97.76%和98.70%。
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Zinc Oxide Nanoparticles (ZnONPs) Photocatalyst using Pulse Laser Ablation Method for Antibacterial in Water Polluted
Synthesis of zinc oxide nanoparticles by pulse laser ablation method has been successed carried out. Synthesis was carried out in aquades medium with a repetition rate variation of 5 Hz, 10 Hz and 15 Hz pulse laser yielding brown colloids. The higher laser repetition rate, the colloidal color will be more dark brown. Characterization of zinc oxide nanoparticles includes UV-Vis, SEM-EDX, FTIR and XRD. The image of SEM shows that zinc oxide nanoparticles have a round shape. Measurement of particle distribution with imageJ software from SEM images showed that ZnO nanoparticles were 23.63 nm, 12.13 nm and 5.59 nm for 5 Hz, 10 Hz and 15 Hz shots. The EDX spectrum analysis results show that only Zn and O atoms in the ZnO nanoparticles colloid are synthesized. FTIR results showed that sprocket ZnO was formed at wave number 457 cm-1 and 545 cm-1. The XRD analysis results also show some peaks known as the ZnO phase. This indicates that ZnO nanoparticles have been formed. The testing of the antibacterial activity of ZnO nanoparticles using a liquid dilution method with nanoparticle concentrations of 40 ppm, 60 ppm and 80 ppm. The test results showed the percentage of degradation of Escherichia coli bacteria at concentrations of 40 ppm, 60 ppm and 80 ppm respectively at 89.60%, 97.76% and 98, 70%.
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